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Hazmat means hazardous material. A hazardous material is a substance or material that the U.S. DOT has determined can pose an unreasonable risk to health, safety, and property when transported in commerce, and has been designated as hazardous under federal hazmat transportation law. The term includes hazardous substances, hazardous wastes, marine pollutants, elevated temperature materials, materials in the Hazardous Materials Table, and materials that meet the defining criteria for hazard classes and division.
There are nearly 1 million shipments of hazardous materials by land, sea, and air across the United States each day.
Because hazardous materials can harm people, property, and the environment if not handled, packaged, and transported correctly, the transportation of hazardous materials is highly regulated. Strict standards and regulations are in place for those who are offering hazardous materials for transportation, those who are transporting hazardous materials, and even those who are designing and manufacturing the packaging used to contain hazardous materials.
The standards and regulations are enforced by various federal agencies, all with the common goal to protect the public and everyone involved in hazardous materials transportation.
The regulatory authority for hazardous materials transportation in the United States resides with the federal government. The agencies below assist with regulating, implementing, and enforcing policies for the transportation of hazardous materials:
The Pipeline and Hazardous Materials Safety Administration’s (PHMSA) mission is to protect people and the environment by advancing the safe transportation of energy and other hazardous materials that are essential to our daily lives. To accomplish this, PHMSA establishes national policy, sets and enforces standards, educates, and conducts research to prevent incidents. PHMSA also prepares the public and first responders to reduce consequences if an incident should occur.
PHMSA has five primary goals that it keeps in mind when developing new regulations or revising older ones:
Historical note
PHMSA is a U.S. Department of Transportation (DOT) agency. It was created under the Norman Y. Mineta Research and Special Programs Improvement Act of 2004. This act changed the agency’s name from Research and Special Programs Administration (RSPA) to Pipeline and Hazardous Materials Administration (PHMSA).
PHMSA is composed of two safety offices that are responsible for regulating the safe movement of hazardous materials.
Office of Hazardous Materials Safety
The Office of Hazardous Materials Safety (OHMS) develops and recommends regulatory changes governing the multimodal transportation of hazardous materials. It develops long- and short-term plans, schedules hazardous materials regulatory actions, and carries them out in accordance with the plan. When proposed regulations apply only to a single mode of transportation, OHMS develops and coordinates those regulations with the appropriate operating administration.
OHMS responds to requests for interpretation of regulations, inconsistency rulings, and non-preemption determinations. OHMS also conducts public hearings in conjunction with regulatory changes, issues special permits where needed (consulting with the DOT as appropriate), and makes final determinations on registration approvals and reconsideration petitions.
OHMS’s primary duty is to develop regulatory policy options and initiatives based on social, economic, technological, environmental, and safety impacts of regulatory, legislative, or program activities that involve hazardous materials transportation. The office participates fully in policy determinations and implements guidance for approved policies within its authority.
Office of Pipeline Safety
The Office of Pipeline Safety (OPS) administers the national regulatory program to ensure the safe, reliable, and environmentally sound operation of the nation’s natural gas and hazardous liquid pipeline transportation system. OPS develops regulations and other approaches to risk management to assure safety in design, construction, testing, operation, maintenance, and emergency response of pipeline facilities. Since 1986, the entire pipeline safety program has been funded by a user fee assessed on a per-mile basis on each pipeline operator OPS regulates.
OPS also:
Several other federal bodies are involved in regulating the transport of hazardous materials. These include the United States Coast Guard (USCG), the Federal Motor Carrier Safety Administration (FMCSA), the Federal Railroad Administration (FRA), the Federal Aviation Administration (FAA), and the Occupational Safety & Health Administration (OSHA).
United States Coast Guard
The USCG enforces the domestic regulations for the transportation of hazardous materials by vessel. They may board any vessel in U.S. waters to enforce the Hazardous Materials Regulations (HMR) and may inspect:
Federal Motor Carrier Safety Administration
FMCSA is responsible for regulating operational standards for companies and individuals operating trucks, vans, buses, and other commercial motor vehicles involved in interstate commerce. FMCSA’s primary mission is to reduce crashes, injuries, and fatalities involving large trucks and buses.
In order to accomplish its primary mission, FMCSA’s strategy is to:
Federal Railroad Administration
The FRA’s mission is to enable the safe, reliable, and efficient movement of people and goods for a strong America, now and in the future. FRA regulates more than 760 railroads (including 27 passenger, 8 switching and terminal, 134 tourist/excursion/historical, and 640 freight railroads).
The mission is primarily accomplished through:
Seven offices make up the FRA structure. However, the Office of Railroad Safety (ORS) is responsible for the safe transportation of hazmat by rail. The ORS administers a safety program that oversees the movement of hazardous materials (including hazmat), such as petroleum, chemicals, and nuclear products, throughout national and international rail transportation systems.
Federal Aviation Administration
The FAA is responsible for the regulation and oversight of civil aviation within the United States, as well as operation and development of the National Airspace System. Its primary mission is to ensure the safety of civil aviation.
The FAA regulates and oversees all aspects of civil aviation, including:
Occupational Safety and Health Administration
OSHA is responsible for ensuring safe and healthful conditions for employees in the workplace. To accomplish this, OSHA sets and enforces standards and provides training, outreach, education, and compliance assistance.
OSHA developed the Hazard Communication Standard (HCS) as a way to protect workers from chemical hazards. HCS is designed to ensure that the hazards of all chemicals produced or imported are evaluated and that information regarding these hazards is available to all workers. The details for HCS are communicated through labels and Safety Data Sheets (SDS).
Caution: OSHA’s Hazard Communication Standard (HCS) pictograms look very similar to the Department of Transportation (DOT) hazmat labels, but they are not authorized for use during transportation. HCS pictograms can be on a package with DOT hazmat labels provided they are part of a complete HCS label.
Enforcement of the Hazardous Materials Regulations (HMR) is conducted by many agencies at the federal, state, indigenous people reservation, county, and city levels. The U.S. Department of Transportation’s (DOT) Pipeline and Hazardous Materials Safety Administration (PHMSA) is responsible for maintaining and updating the HMR in 49 CFR Parts 100-180. PHMSA also has an enforcement office that inspects entities that do the following:
Other federal agencies enforce the HMR for the modes of transport that they regulate, such as the Federal Motor Carrier Safety Administration (FMCSA) for highway transport, Federal Aviation Administration (FAA) for air, Federal Railroad Administration (FRA) for rail, and Coast Guard for water.
States also adopt and enforce the federal HMR. State HMR enforcement concentrates primarily on highway transport. For information on state hazardous materials requirements see State Information.
Some indigenous people tribes, counties, and cities also enforce the HMR. What they enforce and the penalties they impose vary.
Information on federal civil and criminal violations of the Hazardous Materials Regulations can be found in Part 107, Subpart D of the Hazardous Materials Regulations. According to 107.329, a person who violates a requirement in the regulations is liable for a civil penalty of not more than $84,425 and not less than $508 for each violation.
However:
Examples of PHMSA violations and possible penalties can be found in Appendix A to Subpart D of Part 107 of the Hazardous Materials Regulations. This appendix provides guidelines to be used by PHMSA’s Office of Hazardous Materials Safety (OHMS) in making initial determinations for civil penalties.
Reciprocity surrounding the HMR
The HMR allow the use of other regulations for the transport of hazardous materials/dangerous goods into and out of the United States.
There are specific limitations and requirements depending on what is being transported, mode of transport, and what other regulations are being used. The specifics on what is allowed can be found in the following sections of Part 171 of the HMR:
The hazardous materials regulations apply to those involved in three primary types of activities: pre-transportation functions, transportation functions, and hazardous materials packaging.
Pre-transportation functions include activities that would be performed by a person offering hazardous materials for transportation in commerce, also known as a hazardous materials shipper. These pre-transportation functions would include:
Transportation functions include activities that would be performed by those directly involved in transporting hazardous materials, including drivers. Transportation functions would include:
The Pipeline and Hazardous Materials Safety Administration (PHMSA) issues all rules that change the Hazardous Materials Regulations (HMR).
PHMSA often issues an Advanced Notice of Proposed Rulemaking (ANPRM) that discusses suggested changes and requests comments on the possible options.
If the changes are not very complicated, or after comments from an ANPRM have been reviewed, a Notice of Proposed Rulemaking (NPRM) is issued. The NPRM has the exact wording and changes as they could appear in a final rule. Comments on the proposed changes are requested.
After comments on an NPRM are reviewed, a final rule is issued. This contains the changes to the regulations. The changes may become effective on the date of publication or at a date specified in the rulemaking. The date when the changes become effective is when the regulations actually change. Compliance with the changes may be mandatory on the effective date, or it could be delayed, in some cases for several years.
Even after the final rule is issued, comments can still be submitted, and appropriate changes may be made by PHMSA. If these changes are made, they will be issued in another final rule.
The hazardous materials regulations (HMR) and the Federal Motor Carrier Safety Regulations (FMCSRs) both fall under the Department of Transportation. The regulations, however, are handled separately by two agencies: the Pipeline and Hazardous Materials Safety Administration (PHMSA) and the Federal Motor Carrier Safety Administration (FMCSA), respectively.
The FMCSA enforces on-road hazardous materials regulations for interstate carriers with a USDOT (U.S. Department of Transportation) number and intrastate-only carriers transporting placarded hazardous materials. Motor carrier performance, including hazardous materials compliance, is tracked under FMCSA’s Compliance Safety Accountability (CSA) program.
The FMCSRs contain limited hazardous materials transportation requirements in Part 397. This part covers hazardous materials transportation requirements, specifically the driving, parking, and hazardous materials routing rules when transporting hazardous materials.
The requirement for an FMCSA hazardous materials safety permit (when hauling certain materials) is found in Part 385.
Throughout the Hazardous Materials Regulations (HMR), there are exceptions to the regulations. These exceptions provide relief from requirements in the regulations.
In many situations, the relief is authorized only if specific requirements are met. Anyone can use these exceptions, as long as they meet all the requirements.
Some examples of exceptions include:
Exceptions for limited quantities and consumer commodities for a wide range of hazards can be found in sections 173.150 to 173.156.
Limited quantities are smaller amounts of hazardous materials in non-bulk combination packages. A limited quantity exception can only be used for a hazardous material if Column 8A of the Hazardous Materials Table (HMT) references the specific section in Part 173 that contains the exception.
The sections in Part 173 that contain the limited quantity requirements for the different hazard classes and divisions are as follows, with examples:
Packaging
Limited quantity packaging must conform to the specifications, quantity, and weight limits specified for each hazard class/division and packing group. These specifications are listed in the section in Part 173 (listed in Column 8A of the HMT) that is applicable to the material.
Except for Class 1 and 7, each combination package may not exceed 66 pounds (30 kg) gross weight. The size of inner packagings that are allowed to be used varies depending on the hazard/division and packing group of the material.
For example, Class 8 materials in Packing Group III must be in inner packagings not more than 1.3 gallons (5 L) for liquids or 11 pounds (5 kg) for solids. These inner packagings must be packed in a strong outer packaging.
Markings
A package containing a limited quantity of hazardous materials must be marked as follows:
The width of the border forming the square-on-point marking must be at least 2 mm. Each side of the marking must be at least 100 mm.
If the size of the package requires a smaller marking, then each side of the marking may be reduced to no less than 50 mm. For cargo transport units transported by water, each side of the marking must have a minimum size of 250 mm. (172.315)
Labels
Labels are not required for most limited quantities of hazardous materials. However, labels are required for a limited quantity transported by aircraft and for poison-by-inhalation materials. (173.150 - 173.155)
Shipping papers
In most situations, shipping papers are not required for a limited quantity of hazardous material. However, shipping papers are required for a limited quantity of a hazardous material that is a hazardous substance, hazardous waste, or marine pollutant, or is offered/transported by air or water. When a shipping paper is required, the words “Limited Quantity” or the abbreviation “Ltd Qty” must follow the basic description for the hazardous material. (172.203)
Training
If an employer offers or transports limited quantities, their employees are performing functions subject to the Hazardous Materials Regulations (HMR) and must receive hazmat training. Before these hazmat employees perform any function, they must be trained, tested, and certified as required by the HMR. (172.704)
Exceptions
Listing an emergency response telephone number on the shipping papers is not required for limited quantities. (172.604(c))
Most limited quantities are excepted from the specification packaging, shipping papers, labeling, and placarding requirements. Examples of this can be found in 173.150 through 173.155.
The exceptions section in Part 173 (listed in Column 8A of the HMT) gives the exceptions allowed and the requirements that must be met to offer and transport each specific material as a limited quantity.
Materials of trade (MOTs) are hazardous materials that are carried on a motor vehicle:
Hazard and Size Limitations
A material of trade (not including self-reactive material, poisonous by inhalation material, or hazardous waste) is limited to:
Gross weight
The gross weight of all MOTs on a motor vehicle may not exceed 440 pounds (200 kg), not including 400 gallons (1,500 L) or less of a diluted mixture of Class 9 material, as mentioned above. (173.6)
Markings
A non-bulk packaging, other than a cylinder, must be marked with a common name or proper shipping name to identify the material it contains (such as spray paint or isopropyl alcohol).
If the packaging contains a reportable quantity of a hazardous substance, the letters “RQ” must be included.
A bulk packaging containing a diluted mixture (≤2%) of a Class 9 material must be marked on two opposing sides with the identification number. (173.6)
Packagings
Packaging for MOTs must be leak tight for liquids and gases; sift proof for solids; and securely closed, secured against shifting, and protected against damage. Each material must be packaged in the manufacturer’s original packaging or a packaging of equal or greater strength and integrity. Packaging for gasoline must be made of metal or plastic and conform to the Hazardous Materials Regulations (HMR) or Occupational Safety & Health Administration (OSHA) regulations.
Outer packagings are not required for receptacles (e.g., cans and bottles) or articles that are secured against shifting in cages, carts, bins, boxes, or compartments, or by other means. (173.6)
Cylinders
A cylinder or other pressure vessel containing a Division 2.1 or 2.2 material must conform to the marking, labeling, packaging, qualification, maintenance, and use requirements of the HMR, except that outer packagings are not required. Manifolding of cylinders is authorized provided all valves are tightly closed. (173.6)
Drivers
The operator of a motor vehicle that contains MOTs must be informed of the presence of the material and must be informed of the MOTs requirements in HMR section 173.6.
Exceptions
The MOTs regulations do not require:
The MOTs regulations do require:
Packaging exceptions are applied in certain situations where normal packaging requirements cannot be met.
All packagings of hazardous materials, regardless of the mode of transportation, must be as specified in Part 173, unless exceptions are authorized. Some exceptions include:
Salvage drums
Packages of hazardous materials that are damaged, defective, or found leaking and hazardous materials that have spilled or leaked may be placed in a salvage drum for transport to be repackaged or for disposal. The salvage drum must be metal or plastic, have a removable head, and be compatible with the lading.
The salvage drum must be shipped under the following conditions:
Placarding exemption for 1,001 pounds or less
A transport vehicle or freight container that contains less than 1,001 pounds (454 kg) aggregate gross weight of hazardous materials in non-bulk packages covered by Table 2 is not required to display placards. (This exception does not apply to bulk packages or materials with subsidiary hazards that must be placarded according to Section 172.505.) (172.504)
Marine pollutants transported by water, in any size packaging, are subject to all the applicable requirements. Marine pollutants transported by highway, rail, or air are subject to the requirements only when transported in bulk packages. (171.4)
Shipping papers
For materials that are marine pollutants, the words “Marine Pollutant" must be entered on the shipping paper in association with the basic description. In addition, if the name of the component that makes a material a marine pollutant is not identified in the proper shipping name, it must be added in parentheses in association with the basic description. If two or more components are involved, the two components most predominantly contributing to the marine pollutant designation must be listed. (172.203[l])
Markings
The marine pollutant marking shows a dead fish floating in black water near a leafless tree, as seen here:
Non-bulk packagings that contain marine pollutants and are offered for transportation by vessel must be marked with:
Bulk packagings with a capacity of 3,785 L (1,000 gallons) or more must be marked on each side and each end with the marine pollutant marking.
Bulk packagings with a capacity of less than 3,785 L (1,000 gallons) must be marked on two opposing sides with the marine pollutant marking.
The marine pollutant marking must meet the following specifications:
Marking exceptions
Non-bulk packagings of marine pollutants transported by motor vehicle, rail car, or aircraft are not subject to the marine pollutant requirements. (171.4)
A bulk packaging that bears a label or placard is not required to display the marine pollutant marking, unless it’s being transported by vessel. (172.322)
A package of limited quantity material marked with a square-on-point limited quantity marking is not required to display the marine pollutant marking. (172.322)
When offered for transportation by vessel, the marine pollutant marking is not required on single packagings or combination packagings where each single package or each inner packaging of combination packagings has:
When offered for transportation by vessel, the marine pollutant marking is not required on a combination packaging containing a non-severe marine pollutant in inner packagings, each of which contains:
Immediate reporting
Immediate notice is required after a release of a marine pollutant in a quantity exceeding 450 L (119 gallons) for liquids or 400 kg (882 pounds) for solids.
Severe marine pollutants
The materials listed in Column 2 of the table in Appendix B to 172.101 have been identified by the International Maritime Organization (IMO) as environmentally hazardous or marine pollutants. Those considered most hazardous are designated as “severe marine pollutants” and identified by the letters “PP” in Column 1.
Severe marine pollutants are subject to the regulations when in a mixture or solution and packaged in a concentration that equals or exceeds 1 percent by weight of the mixture or solution.
Combustible liquids that are in non-bulk packaging and are not a hazardous substance, hazardous waste, or marine pollutant are not subject to the Hazardous Materials Regulations (HMR) (173.150[f][2]).
Furthermore, combustible liquids that are:
are only subject to the hazmat regulations specified in 173.150(f)(3). This does not include labeling or security plans.
For shipments involving any air, water, or international movement, these materials are considered Class 3 (flammable) materials.
Combustible and flammable liquids
Combustible liquid is defined as any liquid that doesn’t fit the definition of any other hazard class and has a flashpoint higher than 140° but less than 200°F (60° to less than 93°C). (173.120[b][1])
A flashpoint is the minimum temperature at which a liquid gives off vapor within a test vessel in sufficient concentration to form an ignitable mixture with air near the surface of the liquid.
Class 3 (flammable) materials with flashpoints of 100° to 140°F (38° to 60°C) that do not meet the definition of any other hazard class are classed as a “combustible liquid” for transportation by highway and rail. (173.120[b][2])
Flammable liquid is defined as either:
Bulk packaging requirements
Bulk packagings are packagings in which hazardous materials are loaded with no intermediate form of containment. These include transport vehicles and freight containers, but not vessels or barges.
To be defined as a bulk packaging, a packaging must have:
A Large Packaging in which hazardous materials are loaded with an intermediate form of containment, such as one or more articles or inner packagings, also counts as a bulk packaging.
A national registration program, including an annual fee, is in place for people who offer for transport or transport certain hazardous materials. The annual fee funds a nationwide emergency response training and planning grant program for states, indigenous tribes, and local communities.
Who must register?
The Pipeline and Hazardous Materials Safety Administration’s (PHMSA) hazardous materials registration and fee requirements apply to any person who offers for transport or transports in foreign, interstate, or intrastate commerce any of the following:
Exceptions
The following are exempt from the registration and fee requirements:
Hazmat safety permit
Certain carriers of hazardous materials must obtain a Federal Motor Carrier Safety Administration (FMCSA) Hazardous Materials Safety Permit. A hazardous materials safety permit is required only if transporting the types of hazardous materials listed in 385.403:
New entrant carriers use the MCSA-1 form to obtain the permit. Existing carriers use the MCS-150B “Combined Motor Carrier Identification Report and HM Permit Application” to complete the biennial update.
PHMSA registration vs. Hazmat safety permit
There’s sometimes confusion surrounding the PHMSA registration requirement and the FMCSA hazardous materials safety permit.
One way to differentiate between the two is to remember that the PHMSA registration applies to a larger and wider group of hazmat transporters and shippers. Transporting or shipping placarded hazmat can make a hazmat transporter or shipper subject to the PHMSA registration.
The FMCSA hazmat safety permit applies to a smaller number of motor carriers involved in transporting hazmat that is more hazardous in nature, including explosives, radioactives, poisonous by inhalation materials, and methane or natural gas.
Hazmat training for each hazmat employee is one of the most important steps to take to ensure the safe movement of hazardous materials. The hazmat employer is responsible for training each hazmat employee to fulfill Pipeline and Hazardous Materials Safety Administration (PHMSA) requirements.
Training
A hazmat employee is an individual, including a self-employed individual, who during the course of employment performs any function subject to the Hazardous Materials Regulations (HMR). Before any hazmat employee performs any function subject to the HMR, the employee must be trained, tested, and certified by the hazmat employer. (172.702)
An employee may perform hazmat job functions before completing hazmat training, provided:
Training content
Hazmat employee training must include the following types of training:
Any entity that offers for transportation or transports in commerce one or more of the hazardous materials listed in 172.800(b)(1)-(16) must develop and implement a security plan.
Security plans must address the following elements:
The security plan must be reviewed at least annually and revised and/or updated as necessary to reflect changes in circumstances. The plan, including the risk assessment, must be in writing and must be retained as long as it remains in effect.
Entities must develop and adhere to a security plan for hazardous materials if they offer for transportation in commerce or transport in commerce one or more of the following:
Exceptions for hazmat security plans
Most farmers are not subject to the security plan requirements. The transportation activities of a farmer who generates less than $500,000 annually in gross receipts from the sale of agricultural commodities or products are not subject to the security plan requirements if such activities are:
The security plan requirements also do not apply to combustible liquids that are not a hazardous substance, hazardous waste, or marine pollutant in non-bulk packaging, because these are not subject to the Hazardous Materials Regulations (HMR) in general.
In addition, the security plan requirements in Part 172, Subpart I are not listed as required compliance for combustible liquids in bulk packaging or combustible liquids that are also a hazardous substance, hazardous waste, or marine pollutant. (173.150[f])
Additional requirements for rail
Each rail carrier transporting one or more of the following materials is subject to additional safety and security planning requirements:
The additional safety and security planning requirements include:
Each rail carrier must ensure that its safety and security plan includes all of the following:
Each rail carrier must maintain the above information so it is accessible at or through the carrier’s principal place of business and retain this information for a minimum of two years.
In-depth security training requirements
Each hazmat employee of a person/company that is required to have a security plan must be trained on the security plan and its implementation. This training must include:
Security awareness training
Every hazmat employee must receive security awareness training. New hazmat employees must receive the training within 90 days of employment.
This training must provide an awareness of security risks associated with hazardous materials transportation and methods designed to enhance transportation security. It must also include a component covering how to recognize and respond to possible security threats.
Each plan must include an assessment of possible transportation security risks for shipments of hazardous materials, including site-specific or location-specific risks associated with facilities at which the materials are prepared for transport, stored, or unloaded incidental to movement, and appropriate measures to address these risks. Specific measures may vary depending upon the level of threat.
At a minimum, a security plan must consist of the following elements:
In addition, a security plan must also include:
Handling sensitive security information
Security plans must be marked as Sensitive Security Information (SSI) as required by 49 CFR 15.13. Security plans on paper must include the protective marking “SENSITIVE SECURITY INFORMATION” at the top and the distribution limitation warning at the bottom of:
The distribution limitation warning must read as follows:
Non-paper security plans must be clearly and conspicuously marked with the protective marking and distribution limitation warning so that a viewer or listener is reasonably likely to see or hear them when obtaining access to the security plan.
Security plan retention and revision
The security plan, including the risk assessment, must be in writing and must be retained as long as it remains in effect. Copies must be made available to those employees who are responsible for implementing it, consistent with personnel security clearance or background investigation restrictions and demonstrated need to know.
The security plan must be reviewed at least annually and revised and/or updated as necessary to reflect changes in circumstances. When the plan is updated or revised, all employees responsible for implementing it must be notified. All copies of the plan must be maintained as of the date of the most recent revision.
A copy of the security plan or an electronic file must be maintained at the employer’s principal place of business and must be made available upon request, at a reasonable time and location, to an authorized Department of Transportation (DOT) or Department of Homeland Security (DHS) official.
Each person in physical possession of a hazardous material must report a hazardous materials incident in writing, by phone, or both.
Two important distinctions should be made:
General reporting requirements are in effect for all modes of transport, including air, rail, vessel and highway. In addition, specific additional requirements govern each mode of transport.
Special requirements for vessel carriers
Carriers by vessel are subject to specific additional requirements when accidents occur on vessel and hazardous materials are involved.
When an accident involves hazardous materials and endangers the safety of the vessel, passengers, or crew, the “master” of the vessel must adopt procedures to achieve maximum safety for all concerned. If the accident results in damaged packages of hazardous materials, or results in the emergency use of packagings not authorized under the Hazardous Materials Regulations (HMR), these packages may not be offered to any forwarding carrier for continued transportation. The master must notify the nearest Captain of the Port of the U.S. Coast Guard for further instructions on the disposition of such packages.
Whenever a fire occurs or another hazardous condition exists on board a vessel carrying hazardous materials, the master must notify the nearest Captain of the Port as soon as possible and comply with instructions received.
If a package, freight container, portable tank, or highway or rail vehicle containing a hazardous material is jettisoned or lost, the master must notify the nearest Captain of the Port as soon as possible and provide the location, quantity, and type of material lost.
After any hazardous material incident, the National Response Center must be notified as soon as practical, but no later than 12 hours after the incident. The notice must be made by the person in physical possession of the hazardous material.
Immediate notice is required whenever any of the following occur during transportation in commerce (including loading, unloading, and temporary storage).
As a direct result of hazardous materials:
Immediate notice of a hazardous materials incident must be provided to the National Response Center by calling (800) 424-8802.
Callers who are reporting hazardous material incidents should be prepared to provide the following information:
Each person in physical possession of a hazardous material at the time of an incident must submit a Hazardous Materials Incident Report. A report must be made within 30 days of discovery of an incident arising out of the transportation, loading, unloading, or temporary storage of hazardous materials as follows:
The report must be filed on DOT Form F5800.1, Hazardous Materials Incident Report. Completed forms F5800.1 must be filed with:
In place of an incident report on a paper form, an electronic incident report may be submitted at http://hazmat.dot.gov.
A copy of the report must be retained at the reporting person’s principal place of business for two years. If the report is maintained somewhere else, it must be made available at the reporting person’s principal place of business within 24 hours of a request by an authorized official.
See DOT Guide for Preparing Hazardous Materials Incident Reports for instructions on proper completion of F5800.1.
Except when immediate phone notice is required (171.15), Hazardous Materials Incident Reports are not required for the following incidents:
The incident report must be updated within one year of the date of occurrence of the incident whenever:
Under provisions of Part 107, Subpart B of the Hazardous Materials Regulations (HMR), the Pipeline and Hazardous Materials Safety Administration (PHMSA) has the authority to grant special permits or administrative relief from the HMR based on equivalent levels of safety as provided in the regulations, or levels of safety consistent with the policy of the Transportation Safety Act. These special permits may allow, for example, a particular hazardous material to be shipped in a packaging that is not specified by the regulations.
Special permits
Special permits are based on the applicant’s ability to demonstrate that a special provision achieves a level of safety at least equal to that required by the regulations — or, if a required safety level does not exist, that it is consistent with the public interest.
Applications for special permits are most often submitted by the shipper for a given product or class of product. However, some applications are submitted by package manufacturers with a packaging that is not currently authorized by the regulations but that they feel meets the needs of shippers and offers the same degree of safety as the authorized packagings.
Special permits are granted for a given length of time and must be renewed periodically. The request for renewal must be submitted at least 60 days prior to the expiration date of the special permit.
After a packaging authorized under a special permit has proven itself to meet the safety standards of the regulations, the Office of Hazardous Materials Standards (OHMS) may adopt the special permit as a rule of general application and incorporate it into the regulations.
Many packaging special permits issued to shippers contain special instructions for the carrier. In such instances, the shipper is required to furnish a copy of the special permit to the carrier.
Because of the danger of transporting poison inhalation hazard materials, the Hazardous Materials Regulations (HMR) have special requirements for shipments of materials meeting the definition of Material Poisonous by Inhalation (171.8). If a material meets the criteria for an inhalation hazard, whether listed in the Hazardous Materials Table (HMT) or not, it is subject to the requirements.
There are several things to be aware of when transporting poison inhalation hazard materials.
Shipping papers
For materials that are poisonous by inhalation, the words “Poison-Inhalation Hazard” must be entered on the paper immediately after the shipping description. For gases, “Zone A,” “Zone B,” “Zone C,” or “Zone D” must be included, and for liquids, “Zone A” or “Zone B,” as appropriate. (For anhydrous ammonia, see “Exceptions” section below).
Markings for non-bulk packages
A non-bulk package that contains material that is poisonous by inhalation must be marked “Inhalation Hazard” in association with the required labels or proper shipping name. The inhalation hazard marking is not required if the package bears a poison gas or poison inhalation hazard label displaying the words “inhalation hazard.”
Markings for large quantities of non-bulk packaging
A transport vehicle or freight container must be marked with the identification number specified for the material, on each side and each end, if the following apply:
If the transport vehicle or freight container contains more than one inhalation hazard material that meets the above identification number marking requirement, it must be marked with the identification number for only one material. That one identification number is determined by the following:
Markings for bulk packages
A bulk package that contains material poisonous by inhalation must be marked “Inhalation Hazard” in association with the required labels or placards or the proper shipping name. The inhalation hazard marking is not required if the package bears a poison gas or poison inhalation hazard label or placard displaying the words “Inhalation Hazard.”
Bulk packaging must be marked on two opposing sides with the Inhalation Hazard marking. The marking must meet the following size requirements:
Placards
Any vehicle, freight container, tank, or unit load device that contains a poison inhalation hazard material must be placarded on each side and each end with a “POISON INHALATION HAZARD” or “POISON GAS” placard, as appropriate, in addition to any other required placard.
Exemptions
Anhydrous ammonia transported within the U.S. is treated differently than other poison inhalation hazard materials. Only the words “Inhalation Hazard” must be entered on the shipping paper in association with the shipping description. The requirements in 172.203(m) do not apply.
Non-bulk packages must be marked “Inhalation Hazard” in association with the shipping name and identification number. Bulk packages must be marked with “Inhalation Hazard” on two opposing sides. The subsidiary placarding requirements in 172.505 are not required.
The regulatory authority for hazardous materials transportation in the United States resides with the federal government. The agencies below assist with regulating, implementing, and enforcing policies for the transportation of hazardous materials:
The Pipeline and Hazardous Materials Safety Administration’s (PHMSA) mission is to protect people and the environment by advancing the safe transportation of energy and other hazardous materials that are essential to our daily lives. To accomplish this, PHMSA establishes national policy, sets and enforces standards, educates, and conducts research to prevent incidents. PHMSA also prepares the public and first responders to reduce consequences if an incident should occur.
PHMSA has five primary goals that it keeps in mind when developing new regulations or revising older ones:
Historical note
PHMSA is a U.S. Department of Transportation (DOT) agency. It was created under the Norman Y. Mineta Research and Special Programs Improvement Act of 2004. This act changed the agency’s name from Research and Special Programs Administration (RSPA) to Pipeline and Hazardous Materials Administration (PHMSA).
PHMSA is composed of two safety offices that are responsible for regulating the safe movement of hazardous materials.
Office of Hazardous Materials Safety
The Office of Hazardous Materials Safety (OHMS) develops and recommends regulatory changes governing the multimodal transportation of hazardous materials. It develops long- and short-term plans, schedules hazardous materials regulatory actions, and carries them out in accordance with the plan. When proposed regulations apply only to a single mode of transportation, OHMS develops and coordinates those regulations with the appropriate operating administration.
OHMS responds to requests for interpretation of regulations, inconsistency rulings, and non-preemption determinations. OHMS also conducts public hearings in conjunction with regulatory changes, issues special permits where needed (consulting with the DOT as appropriate), and makes final determinations on registration approvals and reconsideration petitions.
OHMS’s primary duty is to develop regulatory policy options and initiatives based on social, economic, technological, environmental, and safety impacts of regulatory, legislative, or program activities that involve hazardous materials transportation. The office participates fully in policy determinations and implements guidance for approved policies within its authority.
Office of Pipeline Safety
The Office of Pipeline Safety (OPS) administers the national regulatory program to ensure the safe, reliable, and environmentally sound operation of the nation’s natural gas and hazardous liquid pipeline transportation system. OPS develops regulations and other approaches to risk management to assure safety in design, construction, testing, operation, maintenance, and emergency response of pipeline facilities. Since 1986, the entire pipeline safety program has been funded by a user fee assessed on a per-mile basis on each pipeline operator OPS regulates.
OPS also:
Several other federal bodies are involved in regulating the transport of hazardous materials. These include the United States Coast Guard (USCG), the Federal Motor Carrier Safety Administration (FMCSA), the Federal Railroad Administration (FRA), the Federal Aviation Administration (FAA), and the Occupational Safety & Health Administration (OSHA).
United States Coast Guard
The USCG enforces the domestic regulations for the transportation of hazardous materials by vessel. They may board any vessel in U.S. waters to enforce the Hazardous Materials Regulations (HMR) and may inspect:
Federal Motor Carrier Safety Administration
FMCSA is responsible for regulating operational standards for companies and individuals operating trucks, vans, buses, and other commercial motor vehicles involved in interstate commerce. FMCSA’s primary mission is to reduce crashes, injuries, and fatalities involving large trucks and buses.
In order to accomplish its primary mission, FMCSA’s strategy is to:
Federal Railroad Administration
The FRA’s mission is to enable the safe, reliable, and efficient movement of people and goods for a strong America, now and in the future. FRA regulates more than 760 railroads (including 27 passenger, 8 switching and terminal, 134 tourist/excursion/historical, and 640 freight railroads).
The mission is primarily accomplished through:
Seven offices make up the FRA structure. However, the Office of Railroad Safety (ORS) is responsible for the safe transportation of hazmat by rail. The ORS administers a safety program that oversees the movement of hazardous materials (including hazmat), such as petroleum, chemicals, and nuclear products, throughout national and international rail transportation systems.
Federal Aviation Administration
The FAA is responsible for the regulation and oversight of civil aviation within the United States, as well as operation and development of the National Airspace System. Its primary mission is to ensure the safety of civil aviation.
The FAA regulates and oversees all aspects of civil aviation, including:
Occupational Safety and Health Administration
OSHA is responsible for ensuring safe and healthful conditions for employees in the workplace. To accomplish this, OSHA sets and enforces standards and provides training, outreach, education, and compliance assistance.
OSHA developed the Hazard Communication Standard (HCS) as a way to protect workers from chemical hazards. HCS is designed to ensure that the hazards of all chemicals produced or imported are evaluated and that information regarding these hazards is available to all workers. The details for HCS are communicated through labels and Safety Data Sheets (SDS).
Caution: OSHA’s Hazard Communication Standard (HCS) pictograms look very similar to the Department of Transportation (DOT) hazmat labels, but they are not authorized for use during transportation. HCS pictograms can be on a package with DOT hazmat labels provided they are part of a complete HCS label.
Enforcement of the Hazardous Materials Regulations (HMR) is conducted by many agencies at the federal, state, indigenous people reservation, county, and city levels. The U.S. Department of Transportation’s (DOT) Pipeline and Hazardous Materials Safety Administration (PHMSA) is responsible for maintaining and updating the HMR in 49 CFR Parts 100-180. PHMSA also has an enforcement office that inspects entities that do the following:
Other federal agencies enforce the HMR for the modes of transport that they regulate, such as the Federal Motor Carrier Safety Administration (FMCSA) for highway transport, Federal Aviation Administration (FAA) for air, Federal Railroad Administration (FRA) for rail, and Coast Guard for water.
States also adopt and enforce the federal HMR. State HMR enforcement concentrates primarily on highway transport. For information on state hazardous materials requirements see State Information.
Some indigenous people tribes, counties, and cities also enforce the HMR. What they enforce and the penalties they impose vary.
Information on federal civil and criminal violations of the Hazardous Materials Regulations can be found in Part 107, Subpart D of the Hazardous Materials Regulations. According to 107.329, a person who violates a requirement in the regulations is liable for a civil penalty of not more than $84,425 and not less than $508 for each violation.
However:
Examples of PHMSA violations and possible penalties can be found in Appendix A to Subpart D of Part 107 of the Hazardous Materials Regulations. This appendix provides guidelines to be used by PHMSA’s Office of Hazardous Materials Safety (OHMS) in making initial determinations for civil penalties.
Reciprocity surrounding the HMR
The HMR allow the use of other regulations for the transport of hazardous materials/dangerous goods into and out of the United States.
There are specific limitations and requirements depending on what is being transported, mode of transport, and what other regulations are being used. The specifics on what is allowed can be found in the following sections of Part 171 of the HMR:
The Pipeline and Hazardous Materials Safety Administration’s (PHMSA) mission is to protect people and the environment by advancing the safe transportation of energy and other hazardous materials that are essential to our daily lives. To accomplish this, PHMSA establishes national policy, sets and enforces standards, educates, and conducts research to prevent incidents. PHMSA also prepares the public and first responders to reduce consequences if an incident should occur.
PHMSA has five primary goals that it keeps in mind when developing new regulations or revising older ones:
Historical note
PHMSA is a U.S. Department of Transportation (DOT) agency. It was created under the Norman Y. Mineta Research and Special Programs Improvement Act of 2004. This act changed the agency’s name from Research and Special Programs Administration (RSPA) to Pipeline and Hazardous Materials Administration (PHMSA).
PHMSA is composed of two safety offices that are responsible for regulating the safe movement of hazardous materials.
Office of Hazardous Materials Safety
The Office of Hazardous Materials Safety (OHMS) develops and recommends regulatory changes governing the multimodal transportation of hazardous materials. It develops long- and short-term plans, schedules hazardous materials regulatory actions, and carries them out in accordance with the plan. When proposed regulations apply only to a single mode of transportation, OHMS develops and coordinates those regulations with the appropriate operating administration.
OHMS responds to requests for interpretation of regulations, inconsistency rulings, and non-preemption determinations. OHMS also conducts public hearings in conjunction with regulatory changes, issues special permits where needed (consulting with the DOT as appropriate), and makes final determinations on registration approvals and reconsideration petitions.
OHMS’s primary duty is to develop regulatory policy options and initiatives based on social, economic, technological, environmental, and safety impacts of regulatory, legislative, or program activities that involve hazardous materials transportation. The office participates fully in policy determinations and implements guidance for approved policies within its authority.
Office of Pipeline Safety
The Office of Pipeline Safety (OPS) administers the national regulatory program to ensure the safe, reliable, and environmentally sound operation of the nation’s natural gas and hazardous liquid pipeline transportation system. OPS develops regulations and other approaches to risk management to assure safety in design, construction, testing, operation, maintenance, and emergency response of pipeline facilities. Since 1986, the entire pipeline safety program has been funded by a user fee assessed on a per-mile basis on each pipeline operator OPS regulates.
OPS also:
Several other federal bodies are involved in regulating the transport of hazardous materials. These include the United States Coast Guard (USCG), the Federal Motor Carrier Safety Administration (FMCSA), the Federal Railroad Administration (FRA), the Federal Aviation Administration (FAA), and the Occupational Safety & Health Administration (OSHA).
United States Coast Guard
The USCG enforces the domestic regulations for the transportation of hazardous materials by vessel. They may board any vessel in U.S. waters to enforce the Hazardous Materials Regulations (HMR) and may inspect:
Federal Motor Carrier Safety Administration
FMCSA is responsible for regulating operational standards for companies and individuals operating trucks, vans, buses, and other commercial motor vehicles involved in interstate commerce. FMCSA’s primary mission is to reduce crashes, injuries, and fatalities involving large trucks and buses.
In order to accomplish its primary mission, FMCSA’s strategy is to:
Federal Railroad Administration
The FRA’s mission is to enable the safe, reliable, and efficient movement of people and goods for a strong America, now and in the future. FRA regulates more than 760 railroads (including 27 passenger, 8 switching and terminal, 134 tourist/excursion/historical, and 640 freight railroads).
The mission is primarily accomplished through:
Seven offices make up the FRA structure. However, the Office of Railroad Safety (ORS) is responsible for the safe transportation of hazmat by rail. The ORS administers a safety program that oversees the movement of hazardous materials (including hazmat), such as petroleum, chemicals, and nuclear products, throughout national and international rail transportation systems.
Federal Aviation Administration
The FAA is responsible for the regulation and oversight of civil aviation within the United States, as well as operation and development of the National Airspace System. Its primary mission is to ensure the safety of civil aviation.
The FAA regulates and oversees all aspects of civil aviation, including:
Occupational Safety and Health Administration
OSHA is responsible for ensuring safe and healthful conditions for employees in the workplace. To accomplish this, OSHA sets and enforces standards and provides training, outreach, education, and compliance assistance.
OSHA developed the Hazard Communication Standard (HCS) as a way to protect workers from chemical hazards. HCS is designed to ensure that the hazards of all chemicals produced or imported are evaluated and that information regarding these hazards is available to all workers. The details for HCS are communicated through labels and Safety Data Sheets (SDS).
Caution: OSHA’s Hazard Communication Standard (HCS) pictograms look very similar to the Department of Transportation (DOT) hazmat labels, but they are not authorized for use during transportation. HCS pictograms can be on a package with DOT hazmat labels provided they are part of a complete HCS label.
Enforcement of the Hazardous Materials Regulations (HMR) is conducted by many agencies at the federal, state, indigenous people reservation, county, and city levels. The U.S. Department of Transportation’s (DOT) Pipeline and Hazardous Materials Safety Administration (PHMSA) is responsible for maintaining and updating the HMR in 49 CFR Parts 100-180. PHMSA also has an enforcement office that inspects entities that do the following:
Other federal agencies enforce the HMR for the modes of transport that they regulate, such as the Federal Motor Carrier Safety Administration (FMCSA) for highway transport, Federal Aviation Administration (FAA) for air, Federal Railroad Administration (FRA) for rail, and Coast Guard for water.
States also adopt and enforce the federal HMR. State HMR enforcement concentrates primarily on highway transport. For information on state hazardous materials requirements see State Information.
Some indigenous people tribes, counties, and cities also enforce the HMR. What they enforce and the penalties they impose vary.
Information on federal civil and criminal violations of the Hazardous Materials Regulations can be found in Part 107, Subpart D of the Hazardous Materials Regulations. According to 107.329, a person who violates a requirement in the regulations is liable for a civil penalty of not more than $84,425 and not less than $508 for each violation.
However:
Examples of PHMSA violations and possible penalties can be found in Appendix A to Subpart D of Part 107 of the Hazardous Materials Regulations. This appendix provides guidelines to be used by PHMSA’s Office of Hazardous Materials Safety (OHMS) in making initial determinations for civil penalties.
Reciprocity surrounding the HMR
The HMR allow the use of other regulations for the transport of hazardous materials/dangerous goods into and out of the United States.
There are specific limitations and requirements depending on what is being transported, mode of transport, and what other regulations are being used. The specifics on what is allowed can be found in the following sections of Part 171 of the HMR:
The hazardous materials regulations apply to those involved in three primary types of activities: pre-transportation functions, transportation functions, and hazardous materials packaging.
Pre-transportation functions include activities that would be performed by a person offering hazardous materials for transportation in commerce, also known as a hazardous materials shipper. These pre-transportation functions would include:
Transportation functions include activities that would be performed by those directly involved in transporting hazardous materials, including drivers. Transportation functions would include:
The Pipeline and Hazardous Materials Safety Administration (PHMSA) issues all rules that change the Hazardous Materials Regulations (HMR).
PHMSA often issues an Advanced Notice of Proposed Rulemaking (ANPRM) that discusses suggested changes and requests comments on the possible options.
If the changes are not very complicated, or after comments from an ANPRM have been reviewed, a Notice of Proposed Rulemaking (NPRM) is issued. The NPRM has the exact wording and changes as they could appear in a final rule. Comments on the proposed changes are requested.
After comments on an NPRM are reviewed, a final rule is issued. This contains the changes to the regulations. The changes may become effective on the date of publication or at a date specified in the rulemaking. The date when the changes become effective is when the regulations actually change. Compliance with the changes may be mandatory on the effective date, or it could be delayed, in some cases for several years.
Even after the final rule is issued, comments can still be submitted, and appropriate changes may be made by PHMSA. If these changes are made, they will be issued in another final rule.
The hazardous materials regulations (HMR) and the Federal Motor Carrier Safety Regulations (FMCSRs) both fall under the Department of Transportation. The regulations, however, are handled separately by two agencies: the Pipeline and Hazardous Materials Safety Administration (PHMSA) and the Federal Motor Carrier Safety Administration (FMCSA), respectively.
The FMCSA enforces on-road hazardous materials regulations for interstate carriers with a USDOT (U.S. Department of Transportation) number and intrastate-only carriers transporting placarded hazardous materials. Motor carrier performance, including hazardous materials compliance, is tracked under FMCSA’s Compliance Safety Accountability (CSA) program.
The FMCSRs contain limited hazardous materials transportation requirements in Part 397. This part covers hazardous materials transportation requirements, specifically the driving, parking, and hazardous materials routing rules when transporting hazardous materials.
The requirement for an FMCSA hazardous materials safety permit (when hauling certain materials) is found in Part 385.
Throughout the Hazardous Materials Regulations (HMR), there are exceptions to the regulations. These exceptions provide relief from requirements in the regulations.
In many situations, the relief is authorized only if specific requirements are met. Anyone can use these exceptions, as long as they meet all the requirements.
Some examples of exceptions include:
Exceptions for limited quantities and consumer commodities for a wide range of hazards can be found in sections 173.150 to 173.156.
Limited quantities are smaller amounts of hazardous materials in non-bulk combination packages. A limited quantity exception can only be used for a hazardous material if Column 8A of the Hazardous Materials Table (HMT) references the specific section in Part 173 that contains the exception.
The sections in Part 173 that contain the limited quantity requirements for the different hazard classes and divisions are as follows, with examples:
Packaging
Limited quantity packaging must conform to the specifications, quantity, and weight limits specified for each hazard class/division and packing group. These specifications are listed in the section in Part 173 (listed in Column 8A of the HMT) that is applicable to the material.
Except for Class 1 and 7, each combination package may not exceed 66 pounds (30 kg) gross weight. The size of inner packagings that are allowed to be used varies depending on the hazard/division and packing group of the material.
For example, Class 8 materials in Packing Group III must be in inner packagings not more than 1.3 gallons (5 L) for liquids or 11 pounds (5 kg) for solids. These inner packagings must be packed in a strong outer packaging.
Markings
A package containing a limited quantity of hazardous materials must be marked as follows:
The width of the border forming the square-on-point marking must be at least 2 mm. Each side of the marking must be at least 100 mm.
If the size of the package requires a smaller marking, then each side of the marking may be reduced to no less than 50 mm. For cargo transport units transported by water, each side of the marking must have a minimum size of 250 mm. (172.315)
Labels
Labels are not required for most limited quantities of hazardous materials. However, labels are required for a limited quantity transported by aircraft and for poison-by-inhalation materials. (173.150 - 173.155)
Shipping papers
In most situations, shipping papers are not required for a limited quantity of hazardous material. However, shipping papers are required for a limited quantity of a hazardous material that is a hazardous substance, hazardous waste, or marine pollutant, or is offered/transported by air or water. When a shipping paper is required, the words “Limited Quantity” or the abbreviation “Ltd Qty” must follow the basic description for the hazardous material. (172.203)
Training
If an employer offers or transports limited quantities, their employees are performing functions subject to the Hazardous Materials Regulations (HMR) and must receive hazmat training. Before these hazmat employees perform any function, they must be trained, tested, and certified as required by the HMR. (172.704)
Exceptions
Listing an emergency response telephone number on the shipping papers is not required for limited quantities. (172.604(c))
Most limited quantities are excepted from the specification packaging, shipping papers, labeling, and placarding requirements. Examples of this can be found in 173.150 through 173.155.
The exceptions section in Part 173 (listed in Column 8A of the HMT) gives the exceptions allowed and the requirements that must be met to offer and transport each specific material as a limited quantity.
Materials of trade (MOTs) are hazardous materials that are carried on a motor vehicle:
Hazard and Size Limitations
A material of trade (not including self-reactive material, poisonous by inhalation material, or hazardous waste) is limited to:
Gross weight
The gross weight of all MOTs on a motor vehicle may not exceed 440 pounds (200 kg), not including 400 gallons (1,500 L) or less of a diluted mixture of Class 9 material, as mentioned above. (173.6)
Markings
A non-bulk packaging, other than a cylinder, must be marked with a common name or proper shipping name to identify the material it contains (such as spray paint or isopropyl alcohol).
If the packaging contains a reportable quantity of a hazardous substance, the letters “RQ” must be included.
A bulk packaging containing a diluted mixture (≤2%) of a Class 9 material must be marked on two opposing sides with the identification number. (173.6)
Packagings
Packaging for MOTs must be leak tight for liquids and gases; sift proof for solids; and securely closed, secured against shifting, and protected against damage. Each material must be packaged in the manufacturer’s original packaging or a packaging of equal or greater strength and integrity. Packaging for gasoline must be made of metal or plastic and conform to the Hazardous Materials Regulations (HMR) or Occupational Safety & Health Administration (OSHA) regulations.
Outer packagings are not required for receptacles (e.g., cans and bottles) or articles that are secured against shifting in cages, carts, bins, boxes, or compartments, or by other means. (173.6)
Cylinders
A cylinder or other pressure vessel containing a Division 2.1 or 2.2 material must conform to the marking, labeling, packaging, qualification, maintenance, and use requirements of the HMR, except that outer packagings are not required. Manifolding of cylinders is authorized provided all valves are tightly closed. (173.6)
Drivers
The operator of a motor vehicle that contains MOTs must be informed of the presence of the material and must be informed of the MOTs requirements in HMR section 173.6.
Exceptions
The MOTs regulations do not require:
The MOTs regulations do require:
Packaging exceptions are applied in certain situations where normal packaging requirements cannot be met.
All packagings of hazardous materials, regardless of the mode of transportation, must be as specified in Part 173, unless exceptions are authorized. Some exceptions include:
Salvage drums
Packages of hazardous materials that are damaged, defective, or found leaking and hazardous materials that have spilled or leaked may be placed in a salvage drum for transport to be repackaged or for disposal. The salvage drum must be metal or plastic, have a removable head, and be compatible with the lading.
The salvage drum must be shipped under the following conditions:
Placarding exemption for 1,001 pounds or less
A transport vehicle or freight container that contains less than 1,001 pounds (454 kg) aggregate gross weight of hazardous materials in non-bulk packages covered by Table 2 is not required to display placards. (This exception does not apply to bulk packages or materials with subsidiary hazards that must be placarded according to Section 172.505.) (172.504)
Marine pollutants transported by water, in any size packaging, are subject to all the applicable requirements. Marine pollutants transported by highway, rail, or air are subject to the requirements only when transported in bulk packages. (171.4)
Shipping papers
For materials that are marine pollutants, the words “Marine Pollutant" must be entered on the shipping paper in association with the basic description. In addition, if the name of the component that makes a material a marine pollutant is not identified in the proper shipping name, it must be added in parentheses in association with the basic description. If two or more components are involved, the two components most predominantly contributing to the marine pollutant designation must be listed. (172.203[l])
Markings
The marine pollutant marking shows a dead fish floating in black water near a leafless tree, as seen here:
Non-bulk packagings that contain marine pollutants and are offered for transportation by vessel must be marked with:
Bulk packagings with a capacity of 3,785 L (1,000 gallons) or more must be marked on each side and each end with the marine pollutant marking.
Bulk packagings with a capacity of less than 3,785 L (1,000 gallons) must be marked on two opposing sides with the marine pollutant marking.
The marine pollutant marking must meet the following specifications:
Marking exceptions
Non-bulk packagings of marine pollutants transported by motor vehicle, rail car, or aircraft are not subject to the marine pollutant requirements. (171.4)
A bulk packaging that bears a label or placard is not required to display the marine pollutant marking, unless it’s being transported by vessel. (172.322)
A package of limited quantity material marked with a square-on-point limited quantity marking is not required to display the marine pollutant marking. (172.322)
When offered for transportation by vessel, the marine pollutant marking is not required on single packagings or combination packagings where each single package or each inner packaging of combination packagings has:
When offered for transportation by vessel, the marine pollutant marking is not required on a combination packaging containing a non-severe marine pollutant in inner packagings, each of which contains:
Immediate reporting
Immediate notice is required after a release of a marine pollutant in a quantity exceeding 450 L (119 gallons) for liquids or 400 kg (882 pounds) for solids.
Severe marine pollutants
The materials listed in Column 2 of the table in Appendix B to 172.101 have been identified by the International Maritime Organization (IMO) as environmentally hazardous or marine pollutants. Those considered most hazardous are designated as “severe marine pollutants” and identified by the letters “PP” in Column 1.
Severe marine pollutants are subject to the regulations when in a mixture or solution and packaged in a concentration that equals or exceeds 1 percent by weight of the mixture or solution.
Combustible liquids that are in non-bulk packaging and are not a hazardous substance, hazardous waste, or marine pollutant are not subject to the Hazardous Materials Regulations (HMR) (173.150[f][2]).
Furthermore, combustible liquids that are:
are only subject to the hazmat regulations specified in 173.150(f)(3). This does not include labeling or security plans.
For shipments involving any air, water, or international movement, these materials are considered Class 3 (flammable) materials.
Combustible and flammable liquids
Combustible liquid is defined as any liquid that doesn’t fit the definition of any other hazard class and has a flashpoint higher than 140° but less than 200°F (60° to less than 93°C). (173.120[b][1])
A flashpoint is the minimum temperature at which a liquid gives off vapor within a test vessel in sufficient concentration to form an ignitable mixture with air near the surface of the liquid.
Class 3 (flammable) materials with flashpoints of 100° to 140°F (38° to 60°C) that do not meet the definition of any other hazard class are classed as a “combustible liquid” for transportation by highway and rail. (173.120[b][2])
Flammable liquid is defined as either:
Bulk packaging requirements
Bulk packagings are packagings in which hazardous materials are loaded with no intermediate form of containment. These include transport vehicles and freight containers, but not vessels or barges.
To be defined as a bulk packaging, a packaging must have:
A Large Packaging in which hazardous materials are loaded with an intermediate form of containment, such as one or more articles or inner packagings, also counts as a bulk packaging.
Limited quantities are smaller amounts of hazardous materials in non-bulk combination packages. A limited quantity exception can only be used for a hazardous material if Column 8A of the Hazardous Materials Table (HMT) references the specific section in Part 173 that contains the exception.
The sections in Part 173 that contain the limited quantity requirements for the different hazard classes and divisions are as follows, with examples:
Packaging
Limited quantity packaging must conform to the specifications, quantity, and weight limits specified for each hazard class/division and packing group. These specifications are listed in the section in Part 173 (listed in Column 8A of the HMT) that is applicable to the material.
Except for Class 1 and 7, each combination package may not exceed 66 pounds (30 kg) gross weight. The size of inner packagings that are allowed to be used varies depending on the hazard/division and packing group of the material.
For example, Class 8 materials in Packing Group III must be in inner packagings not more than 1.3 gallons (5 L) for liquids or 11 pounds (5 kg) for solids. These inner packagings must be packed in a strong outer packaging.
Markings
A package containing a limited quantity of hazardous materials must be marked as follows:
The width of the border forming the square-on-point marking must be at least 2 mm. Each side of the marking must be at least 100 mm.
If the size of the package requires a smaller marking, then each side of the marking may be reduced to no less than 50 mm. For cargo transport units transported by water, each side of the marking must have a minimum size of 250 mm. (172.315)
Labels
Labels are not required for most limited quantities of hazardous materials. However, labels are required for a limited quantity transported by aircraft and for poison-by-inhalation materials. (173.150 - 173.155)
Shipping papers
In most situations, shipping papers are not required for a limited quantity of hazardous material. However, shipping papers are required for a limited quantity of a hazardous material that is a hazardous substance, hazardous waste, or marine pollutant, or is offered/transported by air or water. When a shipping paper is required, the words “Limited Quantity” or the abbreviation “Ltd Qty” must follow the basic description for the hazardous material. (172.203)
Training
If an employer offers or transports limited quantities, their employees are performing functions subject to the Hazardous Materials Regulations (HMR) and must receive hazmat training. Before these hazmat employees perform any function, they must be trained, tested, and certified as required by the HMR. (172.704)
Exceptions
Listing an emergency response telephone number on the shipping papers is not required for limited quantities. (172.604(c))
Most limited quantities are excepted from the specification packaging, shipping papers, labeling, and placarding requirements. Examples of this can be found in 173.150 through 173.155.
The exceptions section in Part 173 (listed in Column 8A of the HMT) gives the exceptions allowed and the requirements that must be met to offer and transport each specific material as a limited quantity.
Materials of trade (MOTs) are hazardous materials that are carried on a motor vehicle:
Hazard and Size Limitations
A material of trade (not including self-reactive material, poisonous by inhalation material, or hazardous waste) is limited to:
Gross weight
The gross weight of all MOTs on a motor vehicle may not exceed 440 pounds (200 kg), not including 400 gallons (1,500 L) or less of a diluted mixture of Class 9 material, as mentioned above. (173.6)
Markings
A non-bulk packaging, other than a cylinder, must be marked with a common name or proper shipping name to identify the material it contains (such as spray paint or isopropyl alcohol).
If the packaging contains a reportable quantity of a hazardous substance, the letters “RQ” must be included.
A bulk packaging containing a diluted mixture (≤2%) of a Class 9 material must be marked on two opposing sides with the identification number. (173.6)
Packagings
Packaging for MOTs must be leak tight for liquids and gases; sift proof for solids; and securely closed, secured against shifting, and protected against damage. Each material must be packaged in the manufacturer’s original packaging or a packaging of equal or greater strength and integrity. Packaging for gasoline must be made of metal or plastic and conform to the Hazardous Materials Regulations (HMR) or Occupational Safety & Health Administration (OSHA) regulations.
Outer packagings are not required for receptacles (e.g., cans and bottles) or articles that are secured against shifting in cages, carts, bins, boxes, or compartments, or by other means. (173.6)
Cylinders
A cylinder or other pressure vessel containing a Division 2.1 or 2.2 material must conform to the marking, labeling, packaging, qualification, maintenance, and use requirements of the HMR, except that outer packagings are not required. Manifolding of cylinders is authorized provided all valves are tightly closed. (173.6)
Drivers
The operator of a motor vehicle that contains MOTs must be informed of the presence of the material and must be informed of the MOTs requirements in HMR section 173.6.
Exceptions
The MOTs regulations do not require:
The MOTs regulations do require:
Packaging exceptions are applied in certain situations where normal packaging requirements cannot be met.
All packagings of hazardous materials, regardless of the mode of transportation, must be as specified in Part 173, unless exceptions are authorized. Some exceptions include:
Salvage drums
Packages of hazardous materials that are damaged, defective, or found leaking and hazardous materials that have spilled or leaked may be placed in a salvage drum for transport to be repackaged or for disposal. The salvage drum must be metal or plastic, have a removable head, and be compatible with the lading.
The salvage drum must be shipped under the following conditions:
Placarding exemption for 1,001 pounds or less
A transport vehicle or freight container that contains less than 1,001 pounds (454 kg) aggregate gross weight of hazardous materials in non-bulk packages covered by Table 2 is not required to display placards. (This exception does not apply to bulk packages or materials with subsidiary hazards that must be placarded according to Section 172.505.) (172.504)
Marine pollutants transported by water, in any size packaging, are subject to all the applicable requirements. Marine pollutants transported by highway, rail, or air are subject to the requirements only when transported in bulk packages. (171.4)
Shipping papers
For materials that are marine pollutants, the words “Marine Pollutant" must be entered on the shipping paper in association with the basic description. In addition, if the name of the component that makes a material a marine pollutant is not identified in the proper shipping name, it must be added in parentheses in association with the basic description. If two or more components are involved, the two components most predominantly contributing to the marine pollutant designation must be listed. (172.203[l])
Markings
The marine pollutant marking shows a dead fish floating in black water near a leafless tree, as seen here:
Non-bulk packagings that contain marine pollutants and are offered for transportation by vessel must be marked with:
Bulk packagings with a capacity of 3,785 L (1,000 gallons) or more must be marked on each side and each end with the marine pollutant marking.
Bulk packagings with a capacity of less than 3,785 L (1,000 gallons) must be marked on two opposing sides with the marine pollutant marking.
The marine pollutant marking must meet the following specifications:
Marking exceptions
Non-bulk packagings of marine pollutants transported by motor vehicle, rail car, or aircraft are not subject to the marine pollutant requirements. (171.4)
A bulk packaging that bears a label or placard is not required to display the marine pollutant marking, unless it’s being transported by vessel. (172.322)
A package of limited quantity material marked with a square-on-point limited quantity marking is not required to display the marine pollutant marking. (172.322)
When offered for transportation by vessel, the marine pollutant marking is not required on single packagings or combination packagings where each single package or each inner packaging of combination packagings has:
When offered for transportation by vessel, the marine pollutant marking is not required on a combination packaging containing a non-severe marine pollutant in inner packagings, each of which contains:
Immediate reporting
Immediate notice is required after a release of a marine pollutant in a quantity exceeding 450 L (119 gallons) for liquids or 400 kg (882 pounds) for solids.
Severe marine pollutants
The materials listed in Column 2 of the table in Appendix B to 172.101 have been identified by the International Maritime Organization (IMO) as environmentally hazardous or marine pollutants. Those considered most hazardous are designated as “severe marine pollutants” and identified by the letters “PP” in Column 1.
Severe marine pollutants are subject to the regulations when in a mixture or solution and packaged in a concentration that equals or exceeds 1 percent by weight of the mixture or solution.
Combustible liquids that are in non-bulk packaging and are not a hazardous substance, hazardous waste, or marine pollutant are not subject to the Hazardous Materials Regulations (HMR) (173.150[f][2]).
Furthermore, combustible liquids that are:
are only subject to the hazmat regulations specified in 173.150(f)(3). This does not include labeling or security plans.
For shipments involving any air, water, or international movement, these materials are considered Class 3 (flammable) materials.
Combustible and flammable liquids
Combustible liquid is defined as any liquid that doesn’t fit the definition of any other hazard class and has a flashpoint higher than 140° but less than 200°F (60° to less than 93°C). (173.120[b][1])
A flashpoint is the minimum temperature at which a liquid gives off vapor within a test vessel in sufficient concentration to form an ignitable mixture with air near the surface of the liquid.
Class 3 (flammable) materials with flashpoints of 100° to 140°F (38° to 60°C) that do not meet the definition of any other hazard class are classed as a “combustible liquid” for transportation by highway and rail. (173.120[b][2])
Flammable liquid is defined as either:
Bulk packaging requirements
Bulk packagings are packagings in which hazardous materials are loaded with no intermediate form of containment. These include transport vehicles and freight containers, but not vessels or barges.
To be defined as a bulk packaging, a packaging must have:
A Large Packaging in which hazardous materials are loaded with an intermediate form of containment, such as one or more articles or inner packagings, also counts as a bulk packaging.
A national registration program, including an annual fee, is in place for people who offer for transport or transport certain hazardous materials. The annual fee funds a nationwide emergency response training and planning grant program for states, indigenous tribes, and local communities.
Who must register?
The Pipeline and Hazardous Materials Safety Administration’s (PHMSA) hazardous materials registration and fee requirements apply to any person who offers for transport or transports in foreign, interstate, or intrastate commerce any of the following:
Exceptions
The following are exempt from the registration and fee requirements:
Hazmat safety permit
Certain carriers of hazardous materials must obtain a Federal Motor Carrier Safety Administration (FMCSA) Hazardous Materials Safety Permit. A hazardous materials safety permit is required only if transporting the types of hazardous materials listed in 385.403:
New entrant carriers use the MCSA-1 form to obtain the permit. Existing carriers use the MCS-150B “Combined Motor Carrier Identification Report and HM Permit Application” to complete the biennial update.
PHMSA registration vs. Hazmat safety permit
There’s sometimes confusion surrounding the PHMSA registration requirement and the FMCSA hazardous materials safety permit.
One way to differentiate between the two is to remember that the PHMSA registration applies to a larger and wider group of hazmat transporters and shippers. Transporting or shipping placarded hazmat can make a hazmat transporter or shipper subject to the PHMSA registration.
The FMCSA hazmat safety permit applies to a smaller number of motor carriers involved in transporting hazmat that is more hazardous in nature, including explosives, radioactives, poisonous by inhalation materials, and methane or natural gas.
Hazmat training for each hazmat employee is one of the most important steps to take to ensure the safe movement of hazardous materials. The hazmat employer is responsible for training each hazmat employee to fulfill Pipeline and Hazardous Materials Safety Administration (PHMSA) requirements.
Training
A hazmat employee is an individual, including a self-employed individual, who during the course of employment performs any function subject to the Hazardous Materials Regulations (HMR). Before any hazmat employee performs any function subject to the HMR, the employee must be trained, tested, and certified by the hazmat employer. (172.702)
An employee may perform hazmat job functions before completing hazmat training, provided:
Training content
Hazmat employee training must include the following types of training:
Any entity that offers for transportation or transports in commerce one or more of the hazardous materials listed in 172.800(b)(1)-(16) must develop and implement a security plan.
Security plans must address the following elements:
The security plan must be reviewed at least annually and revised and/or updated as necessary to reflect changes in circumstances. The plan, including the risk assessment, must be in writing and must be retained as long as it remains in effect.
Entities must develop and adhere to a security plan for hazardous materials if they offer for transportation in commerce or transport in commerce one or more of the following:
Exceptions for hazmat security plans
Most farmers are not subject to the security plan requirements. The transportation activities of a farmer who generates less than $500,000 annually in gross receipts from the sale of agricultural commodities or products are not subject to the security plan requirements if such activities are:
The security plan requirements also do not apply to combustible liquids that are not a hazardous substance, hazardous waste, or marine pollutant in non-bulk packaging, because these are not subject to the Hazardous Materials Regulations (HMR) in general.
In addition, the security plan requirements in Part 172, Subpart I are not listed as required compliance for combustible liquids in bulk packaging or combustible liquids that are also a hazardous substance, hazardous waste, or marine pollutant. (173.150[f])
Additional requirements for rail
Each rail carrier transporting one or more of the following materials is subject to additional safety and security planning requirements:
The additional safety and security planning requirements include:
Each rail carrier must ensure that its safety and security plan includes all of the following:
Each rail carrier must maintain the above information so it is accessible at or through the carrier’s principal place of business and retain this information for a minimum of two years.
In-depth security training requirements
Each hazmat employee of a person/company that is required to have a security plan must be trained on the security plan and its implementation. This training must include:
Security awareness training
Every hazmat employee must receive security awareness training. New hazmat employees must receive the training within 90 days of employment.
This training must provide an awareness of security risks associated with hazardous materials transportation and methods designed to enhance transportation security. It must also include a component covering how to recognize and respond to possible security threats.
Each plan must include an assessment of possible transportation security risks for shipments of hazardous materials, including site-specific or location-specific risks associated with facilities at which the materials are prepared for transport, stored, or unloaded incidental to movement, and appropriate measures to address these risks. Specific measures may vary depending upon the level of threat.
At a minimum, a security plan must consist of the following elements:
In addition, a security plan must also include:
Handling sensitive security information
Security plans must be marked as Sensitive Security Information (SSI) as required by 49 CFR 15.13. Security plans on paper must include the protective marking “SENSITIVE SECURITY INFORMATION” at the top and the distribution limitation warning at the bottom of:
The distribution limitation warning must read as follows:
Non-paper security plans must be clearly and conspicuously marked with the protective marking and distribution limitation warning so that a viewer or listener is reasonably likely to see or hear them when obtaining access to the security plan.
Security plan retention and revision
The security plan, including the risk assessment, must be in writing and must be retained as long as it remains in effect. Copies must be made available to those employees who are responsible for implementing it, consistent with personnel security clearance or background investigation restrictions and demonstrated need to know.
The security plan must be reviewed at least annually and revised and/or updated as necessary to reflect changes in circumstances. When the plan is updated or revised, all employees responsible for implementing it must be notified. All copies of the plan must be maintained as of the date of the most recent revision.
A copy of the security plan or an electronic file must be maintained at the employer’s principal place of business and must be made available upon request, at a reasonable time and location, to an authorized Department of Transportation (DOT) or Department of Homeland Security (DHS) official.
Entities must develop and adhere to a security plan for hazardous materials if they offer for transportation in commerce or transport in commerce one or more of the following:
Exceptions for hazmat security plans
Most farmers are not subject to the security plan requirements. The transportation activities of a farmer who generates less than $500,000 annually in gross receipts from the sale of agricultural commodities or products are not subject to the security plan requirements if such activities are:
The security plan requirements also do not apply to combustible liquids that are not a hazardous substance, hazardous waste, or marine pollutant in non-bulk packaging, because these are not subject to the Hazardous Materials Regulations (HMR) in general.
In addition, the security plan requirements in Part 172, Subpart I are not listed as required compliance for combustible liquids in bulk packaging or combustible liquids that are also a hazardous substance, hazardous waste, or marine pollutant. (173.150[f])
Additional requirements for rail
Each rail carrier transporting one or more of the following materials is subject to additional safety and security planning requirements:
The additional safety and security planning requirements include:
Each rail carrier must ensure that its safety and security plan includes all of the following:
Each rail carrier must maintain the above information so it is accessible at or through the carrier’s principal place of business and retain this information for a minimum of two years.
In-depth security training requirements
Each hazmat employee of a person/company that is required to have a security plan must be trained on the security plan and its implementation. This training must include:
Security awareness training
Every hazmat employee must receive security awareness training. New hazmat employees must receive the training within 90 days of employment.
This training must provide an awareness of security risks associated with hazardous materials transportation and methods designed to enhance transportation security. It must also include a component covering how to recognize and respond to possible security threats.
Each plan must include an assessment of possible transportation security risks for shipments of hazardous materials, including site-specific or location-specific risks associated with facilities at which the materials are prepared for transport, stored, or unloaded incidental to movement, and appropriate measures to address these risks. Specific measures may vary depending upon the level of threat.
At a minimum, a security plan must consist of the following elements:
In addition, a security plan must also include:
Handling sensitive security information
Security plans must be marked as Sensitive Security Information (SSI) as required by 49 CFR 15.13. Security plans on paper must include the protective marking “SENSITIVE SECURITY INFORMATION” at the top and the distribution limitation warning at the bottom of:
The distribution limitation warning must read as follows:
Non-paper security plans must be clearly and conspicuously marked with the protective marking and distribution limitation warning so that a viewer or listener is reasonably likely to see or hear them when obtaining access to the security plan.
Security plan retention and revision
The security plan, including the risk assessment, must be in writing and must be retained as long as it remains in effect. Copies must be made available to those employees who are responsible for implementing it, consistent with personnel security clearance or background investigation restrictions and demonstrated need to know.
The security plan must be reviewed at least annually and revised and/or updated as necessary to reflect changes in circumstances. When the plan is updated or revised, all employees responsible for implementing it must be notified. All copies of the plan must be maintained as of the date of the most recent revision.
A copy of the security plan or an electronic file must be maintained at the employer’s principal place of business and must be made available upon request, at a reasonable time and location, to an authorized Department of Transportation (DOT) or Department of Homeland Security (DHS) official.