Revised Standards for Hazardous Waste Combustors

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ENVIRONMENTAL PROTECTION AGENCY

40 CFR Parts 60, 63, 260, 261, 264, 265, 266, 270, and 271

	Small incinerators Floor level	Large incinerators Floor level	Floor levels for all incinerators combined
D/F (ng/dscm)	0.2 TEQ or <400°F	0.2 TEQ or <400°F	0.2 TEQ or <400°F.
PM (mg/dscm)	180	180	180
Hg (µg/dscm)	110	130	130
SVM (µg/dscm)	230	270	270
LVM (µg/dscm)	160	880	210
HCl Cl₂ (ppmv)	280	260	280
CO (ppmv)	100	100	100
HC (ppmv)	12	12	12

Pollutant	Wet process kilns Floor level	Dry process kilns Floor level	Floor levels for all incinerators combined
D/F (ng/dscm)	0.2 TEQ or 418°F	0.2 TEQ or 547°F	0.2 TEQ or 418°F.
PM (mg/dscm)	69	69	69
Hg (µg/dscm)	83	150	130
SVM (µg/dscm)	870	57	57
LVM (µg/dscm)	220	49	130
HCl Cl₂ (ppmv)	460	340	640

HAP or standard	CEMS averaging period
PM	2 hours.
Mercury (Hg)	10 hours.
SVM	10 hours.
LVM	10 hours.
HCl and Cl₂	1 hour.
CO	1 hour.
HC	1 hour.

HAP or HAP surrogate	Proposed standards ¹
Dioxin/furans	0.20 ng/dscm TEQ.
Particulate Matter	0.030 gr/dscf. (69 mg/dscm).
Mercury	50 µg/dscm.
SVM [Cd, Pb]	270 µg/dscm.
LVM [As, Be, Cr, Sb]	210 µg/dscm.
HCl Cl₂	280 ppmv.
CO	100 ppmv.
HC	12 ppmv.

HAP or HAP surrogate	Proposed standard ^a
Dioxins/furans	0.2 ng/dscm TEQ.
Particulate matter	69 mg/dscm (0.030 gr/dscf).
Mercury	50 µg/dscm.
SVM [Cd, Pb]	62 µg/dscm.
LVM [As, Be, Cr, Sb]	60 µg/dscm.
HCl Cl₂	67 ppmv.
CO	100 ppmv.
HC	12 ppmv.
^a All emission levels are corrected to 7 percent O₂

	Dioxins	Semi-volatile metals ²	Low volatile metals ³
Existing Sources
Baseline	2E-9 to 9E-5	4E-9 to 7E-7	2E-10 to 4E-6
Floor	3E-9 to 5E-5 4	5E-8 to 5E-7	5E-8 to 8E-6
BTF	3E-9 to 2E-6 5
New Sources
Floor	3E-9 to 5E-5 4	5E-8 to 5E-7	5E-8 to 8E-6
BTF	3E-9 to 2E-6 5.
CEM Option 6		2E-8 to 2E-7	4E-8 to 6E-6
¹ Lifetime excess cancer risk. ² Carcinogenic metal: cadmium. ³ Carcinogenic metal: arsenic, beryllium, and chromium (VI). ⁴ Based on 20 ng/dscm TEQ, the highest level known to be emitted at the floor. ⁵ Based on 0.20 ng/dscm TEQ. ⁶ Based on SVM standard of 60 µg/dscm and LVM standard of 80 µg/dscm (applicable only if the source elects to document compliance using a multi-metals CEM).

	Semi-volatile metals ²	Low volatile metals³	Hydrogen chloride	Chlorine
Existing Sources
Baseline	<0.001 to 0.02	<0.001 to 0.2	0.001 to 0.05	0.008 to 0.7
Floor	<0.001 to 0.01	<0.001 to 0.09	0.02 to 0.05 ⁴	0.07 to 0.3 ⁵
New Sources
Floor	<0.001 to 0.01	<0.001 to 0.09	0.02 to 0.05 ⁴	0.07 to 0.3⁵
BTF	<0.001 to 0.003	<0.001 to 0.03	0.004 to 0.01 ⁴	0.02 to 0.07 ⁵
CEM Option ⁶	<0.001 to 0.004	<0.001 to 0.06.
¹ Hazard quotient.² Cadmium and lead.³ Antimony, arsenic, beryllium, and chromium.⁴ HCl Cl₂ assuming 100 percent HCl.⁵ HCl Cl₂ assuming 10 percent Cl₂⁶ Based on SVM standard of 60 µg/dscm and LVM standard of 80 µg/dscm (applicable only if the source elects to document compliance using a multi-metals CEM).

HAP or HAP surrogate	Proposed standard ^a
Dioxin/furans (TEQ)	0.20 ng/dscm (TEQ).
Particulate Matter	69 mg/dscm (0.030 gr/dscf).
Mercury	50 µg/dscm.
SVM (Cd, Pb)	57 µg/dscm.
LVM (As, Be, Cr, Sb)	130 µg/dscm.
HCl Cl₂ (total chlorides)	630 ppmv.
Hydro-carbons:
Main Stack ^b	20 ppmv.
By-pass Stack ^c	6.7 ppmv.
Carbon Monoxide:
Main Stack	N/A.
By-pass Stack ^c	100 ppmv.
^a All emission levels are corrected to 7 percent O². ^b Applicable only to long wet and dry process cement kilns (i.e., not applicable to preheater and/or precalciner kilns). ^c Emissions standard applicable only for cement kilns configured with a by-pass duct (typically preheater and/or precalciner kilns). Source must comply with either the HC or CO standard in the by-pass duct. A long wet or long dry process cement kiln that has a by-pass duct has the option of meeting either the HC level in the main stack or the HC or CO limit in the by-pass duct.

	Large MWCs	Proposed MWIs	EU HWCs ⁽¹⁾	Proposed HW incinerators	Proposed HW cement kilns	Proposed HW LWAKs
Dioxin/Furan: ng/dscm TEQ and/or Total congeners.	30 Total (or 15 if testing less frequent)	1.9 TEQ or 80 Total	0.19 TEQ	.20 TEQ
PM, mg/dscm	27	30	13 24-hr avg	69 2-hr avg
			13-39 30-min avg (²)
Hg, µg/dscm	80 or 85% Reduct.	470 or 85% Reduct.	130	50 10-hr avg		72 10-hr avg
SVM, µg/dscm	Cd: 40	Cd: 50	Cd: 65	270	57	12.
	Pb: 49	Pb: 100	Tl: 65
			Pb: 130 (³)
LVM, µg/dscm	none	none	1170 (³)	210	130	340.
CO, ppmv	50 to 250 4 to 24 hr avg.	50 12-hr avg	52, 24 hr avg	100 1 hr avg.	Wet and Long, Dry Kilns None.	100 1 hr avg.
			104, 30 min avg (⁴)		Kilns with By-pass 100 in by-pass duct (or HC cannot exceed 6.7) 1 hr avg.
			156, 10 min avg (⁴)
HC, ppmv	None	None	8, 24 hr avg	12 1 hr avg	Wet and Long, Dry Kilns 20 in main stack 1 hr avg. Kilns with By-pass 6.7 in by-pass (or CO cannot exceed 100) 1 hr avg.	14 1 hr avg.
			8-16, 30 min avg (²)
HCl and Cl₂ ppmv as HCl equivalents (⁵)	31 or 95% Reduct	42 or 97% Reduct	8, 24-hr avg 8-48, 30 min avg (²)	280	630	450.
Notes: ¹ The EU HWC guidelines have been corrected from the European basis of 11% O₂ and 0°C to the US basis of 7% O₂ and 20°C. Both are expressed on dry emissions. ² The EU HWC PM, HC, and HCl guidelines are based either 97 % compliance with the lower number or 100% compliance with the higher number on a 30-minute average over a year. ³ The EU LVM guideline is 1300 µg/dscm and includes Sb, As, Pb, Cr, Co, Cu, Mn, Ni, V, Sn. If all metals are emitted equally, their contribution is 130 ₂g /dscm. Pb, a SVM, was subtracted from this group, resulting in the 1170 µg/dscm level. ⁴ The EU HWC CO guideline is based on either 95% compliance with the 156 ppm level on a 10 minute average or 100% compliance with the 104 ppm level on a 30-minute average in any day. ⁵ The proposed MWC and MWI and the EU MWC guideline are for HCl only.

	Large MWCs	MWIs	EU HWCs ¹	Proposed HW incinerators	Proposed HW cement kilns	Proposed HW LWAKs
Dioxin/Furan: ng/dscm TEQ, and/or Total congeners	13 Total (or 7 if testing less frequent)	1.9 TEQ or 80	0.19 TEQ	.20
PM, mg/dscm	24	30 13-39 30-min avg²	13 24-hr avg 69 2-hr avg	69 2-hr avg
Hg, µg/dscm	80 or 85% Reduct	470 or 85% Reduct.	6.5	50 10-hr avg		72 10-hr avg
SVM, µmg/dscm	Cd: 20	Cd: 50	Cd: 3.25	62	55	5.2.
	Pb: 20	Pb: 100	Tl: 3.25
			Pb: 65 ³
LVM, µg/dscm	None	None	585 ³	60	44	55.
CO, ppmv hr avg.	50 to 150 4 to 24	50 12-hr avg 104, 30 min avg ⁴ 156, 10 min avg ⁴	52, 24-hr avg	100 1 hr avg	Wet and Long, Dry Kilns None Kilns with By-pass 100 in by-pass duct (or HC cannot exceed 6.7) 1 hr avg.	100 1 hr avg.
HC	None	None	8, 24 hr avg 8-16, 30 min avg ²	12 1 hr avg	Wet and Long, Dry Kilns 20 in main stack 1 hr avg. Kilns with By-pass 6.7 in by-pass (or CO cannot exceed 100) 1 hr avg	14 1 hr avg.
HCl and Cl₂ ppmv as HCl equivalents⁵	25 or 95% Reduct	42 or 97% Reduct	8, 24-hr avg 8-48, 30 min avg ²	67		62.
Notes: ¹ The EU HWC guidelines have been corrected from the European basis of 11% O₂ and 0°C to the US basis of 7% O₂ and 20°C. Both are expressed on dry emissions. ² The EU HWC PM, HC, and HCl guidelines are based either 97 % compliance with the lower number or 100% compliance with the higher number on a 30-minute average over a year. ³ The EU LVM guideline is 650 µg/dscm and includes Sb, As, Pb, Cr, Co, Cu, Mn, Ni, V, Sn. If all metals are emitted equally, their contribution to the guideline is 65 µg/dscm. Pb, a SVM, was subtracted from this group, resulting in the 585 µg/dscm level. ⁴ The EU HWC CO guideline is based on either 95% compliance with the 156 ppm level on a 10 minute average or 100% compliance with the 104 ppm level on a 30-minute average in any day. ⁵ The proposed MWC and MWI standards and the EU HWC guideline are for HCl only.

HAP	Units	Incinerators Stnd	Cement kilns Stnd	LWA kilns Stnd.
D/F	µg TEQ	0.25	0.23	0.23.
Hg	µg/dscm	13	32	32.
HCl/Cl₂	ppmv	23	25	1800.
SVM	µg/dscm	53	240	61.
LVM	µg/dscm	61	46	57.
PM	gr/dscf	0.024	0.03	0.012.
CO	ppmv	100	n/a	100.
HC	ppmv	12	Main ² :20 by pass ³ :6.7 (or CO 100).	14.
¹ All emissions levels are corrected to 7 percent O₂ ² Applicable only to long wet and dry process cement kilns (i.e., not applicable to preheater and/or precalciner kilns). ³ Emissions standards applicable only for cement kilns configured with a by-pass duct (typically preheater and/or precalciner kilns). Sources must comply with either the HC or CO standard in the by-pass stack.

HAP	Annual emissions at MACT floor level	Percent reduction from baseline emissions (percent)
Dioxin/Furans (TEQ)	3.0 grams TEQ/yr	96
Mercury	0.2 tons/year	96
SVM (Cd, Pb)	1.0 tons/year	98
LVM (As, Cr, Sb, Be)	0.8 tons/year	97
HCl/Cl2	293 tons/year	83
Particulate Matter	650 tons/year	67

HAP	Dry process CKs	Wet Process CKs
Arsenic	3 µg/dscm	32 µg/dscm.
Beryllium	0.3 µg/dscm	24 µg/dscm.
Cadmium	30 µg/dscm	62 µg/dscm.
Chromium	485 µg/dscm	125 µg/dscm.
Chromium (VI)	8 µg/dscm	29 µg/dscm.
Lead	143 µg/dscm	911 µg/dscm.
Mercury	NA	96 µg/dscm.
Dioxins/Furans	1.7 ng/dscm (TEQ)	2.0 ng/dscm (TEQ).

HAP	MACT floor level	BTF levels
Particulate matter	0.030 gr/dscf	0.025 gr/dscf.
Mercury	118 µg/dscm	80 µg/dscm.
Semivolatile metals	261 µg/dscm	150 µg/dscm.
Low-volatile metals	229 µg/dscm	130 µg/dscm.

Pollutant	WTI's recommended standard	EPA's proposed standard
PM (mg/dscm)	33 (0.01 gr/dscf)	69 (0.03 gr/dscf).
SVM (µg/dscm)	167	270.
LVM (µg/dscm)	72	210.

Table V.2.2.-Summary of Proposed Dioxin and Furan Monitoring Requirements
Compliance using	Limits from	Avg. period	How limit is established from comp performance test
Particulate Matter (PM) Control.	PM CEMS	Comp Test 1 hour	10 min Avg over all runs.	Avg of Max 10-min RAs.
Good Combustion. Min comb chamber tempt: CMS at exit of each chamber.	CO and HC CEMS Comp Test.	MACT Std 10 min 11 hour	1 hour Avg of Max 10-min RAs. Avg over all runs.	N/A.
Max waste feedrate CMS For batch fed sources: limit on batch size, feeding frequency, and minimum oxygen.	Comp Test Comp Test	1 hour None		Avg of Max 1 hour RAs. N/A.
Max Inlet Temp to Dry PM APCD	Temp CMS	Comp Test 1 hour	10 min Avg over all runs.	Avg of Max 10 min RAs.
Max Flue Gas Flowrate or Production Rate.	Flowrate CMS or Production Rate.	Comp Test	1 hour	Avg of Max 1 hour RAs
Min Carbon Injection	Feedrate CMS	Comp Test 1 hour	10 min Avg over all runs.	Avg of Min 10 min RAs.
Min Carrier Fluid Flowrate or Nozzle Pressure Drop.	same	Manuf Spec	10 min	N/A.
Carbon Specs	Brand and Type	Comp Test	N/A	Same brand and type.
Max Carbon Age, Carbon bed	Max Carbon lifetime Conf Tests Sub. Comp Tests	Initial Comp Test. N/A N/A	N/A Normal C Change-out Schedule. Max C Age is the age during sub. Comp Tests.	Manuf Specs (no C aging).
Min Flue Gas Temp, Catalytic oxidizer	Inlet to Catalyst.	Comp TesT	10 min	Avg of Min 10 min RAs.
		1 hour	Avg over all runs.
Max Age, Catalytic Oxidizer Catalyst Replacement Specs Loading. Space Time Substrate Construct: mat'ls, pore size.	Time in use Catalytic Metal	Manuf Spec Comp Test	As specified N/A	Same as used during comp test
Max Flue Gas Temp. Catalytic Oxidizer.	Inlet to Catalyst.	Manuf Spec	10 min	As specified.
Min Inhibitor Feedrate	Feedrate CMS	Comp Test	10 min	Avg of Min 10 min RAs.
		1 hour	Avg over all runs.
Inhibitor Specs	None	Comp Test	N/A	Same brand and type.

Table V.2.3.—Proposed Hg Monitoring Requirements and Other Options Being Considered
	Compliance using	Limits from	Avg. period	Operating limit avg pd basis
Proposed Requirement	CEMS	Total Hg or Multi- metal CEMS.	CEMS Std	10 hour
Option 1: Elemental Hg CEMS	Surrogate CEMS	Elemental Hg CEMS	Comp Test	10 hour	Avg over all runs.
Max Flue Gas flowrate or Production Rate.	Same	Comp Test	1 hour	Avg of Max 1 hour RAs
Min Press Drop, Wet scrubber	Pressure Drop across scrubber	Comp Test	10 min 1 hour	Avg of Min 10 min RAs Avg over all runs.
Min Liq Feed Press, Wet Scrubber.	Pressure	Manuf Spec	10 min.
Min Liq pH	pH	Comp Test	10 min. 1 hour	Avg of Min 10 min RAs. Avg over all runs.
Min Liq/Gas Ratio, wet Scrubber.	Scrubber Liquid and Flue Gas Flowrate.	Comp Test	10 min 1 hour	Avg of Min 10 min RAs. Avg over all runs.
Option 2: No CEMS Feedrate all streams.	Max Total Hg	Feedstream Analysis	Comp Test	12 hour	Avg over all runs.
Max Inlet Temp to Dry PM APCD.	Temp	Comp Test	10 min 1 hour	Avg of Max 10 min RAs. Avg over all runs.
Min Carbon Injection Rate.	Feedrate CMS	Comp Test	10 min 1 hour	Avg of Min 10 min RAs. Avg over all runs.
Carbon Specs	Brand and Type	Comp Test	N/A	N/A.
Min Carrier Fluid Flowrate or Nozzle.	Same	Manuf Spec	10 min	N/A
Max Carbon Age	Max Carbon	Initia Conf Tests Subsequent Comp Tests	N/A N/A N/A	Manuf Specs. Normal C Change-out Schedule. Max C Age is the age during subsequent Comp Tests.
Max Flue Gas Flowrate of Production Rate.	Flowrate CMS or Production Rate.	Comp Test	1 hour	Avg of Max 1 hour RAs
Min Press Drop, Wet Scrubber.	Pressure Drop across Scrubber.	Comp Test	10 min 1 hour	Avg of Min 10 min RAs. Avg over all runs.
Min Liq Feed Press, Wet Scrubber.	Pressure	Manuf Spec
Min Liq pH, Wet Scrubber.	pH	Comp Test	10 min 1 hour	Avg of Min 10 min RAs. Avg over all runs.
Min Liq/Gas Ratio, Wet Scrubber.	Scrubber Liquid and Flue Gas Flowrate.	Comp Test	10 min 1 hour	Avg of Min 10 min RAs. Avg over all runs.

Table V.2.4.—Summary of Proposed SVM and LVM Compliance Monitoring Requirements and Other Options Being Considered
	Compliance using	Limit from	Avg period	Operating limit avg pd basis
Proposed Option 1 (facility choice)	CEMS	Multi-metal CEMS	CEMS Std	10 hour
Proposed Option 2	Good PM Control	PM CEMS (see PM for Others)	Comp Test	10 min 1 hour	Avg of Max 10 min RAs. Avg over all runs.
	Max Inlet Temp to Dry PM APCD	Same	Comp Test	10 min 1 hour	Avg of Max 10 min RAs Avg over all runs.
	Max Total SVM and Feedrates.	Feedstream Analysis	Comp Test	12 hour	Avg over all runs
	Max Pumpable LVM Feedrate	Feedstream Analysis	Comp Test	12 hour	Avg over all runs.
	Max Chlorine Feedrate	Feedstream Analysis	Comp Test	12 hour	Avg over all runs.

Table V.2.5.—Proposed HCl/Cl₂ Compliance Monitoring Requirements and Other Options Being Considered
	Compliance using	Limits from	Avg period	Operating Limit avg. period basis
Proposed Option 1 (Facility Choice) or Production Rate.	Max Flue Gas Flowrate	Same	Comp Test	1 hour	Avg of Max 1 hour RAs
Max Chlorine Feedrate	Feedstream Analysis	Comp Test	12 hour	Avg over all runs.
Min Press Drop, Wet Scrubber.	Press drop across scrubber.	Comp Test	10 min 1 hour	Avg of Min 10 min RAs. Avg over all runs.
Min Liq Feed Pressure, Wet Scrubber.	Pressure	Manuf Spec	10 min
Min Liq pH, Wet scrubber	pH	Comp Test	10 min 1 hour	Avg Min 10 min RAs. Avg over all runs.
Min Liq/Gas Ratio, wet scrubber	Scrubber liquid and gas flowrates	Comp Test	10 min 1 hour	Avg Min 10 min RAs. Avg over all runs.
Min Sorbent Feedrate, Dry Scrubber.	Sorbent Feedrate	Comp Test	10 min 1 hour	Avg of Min 10 min RAs Avg over all runs.
Min Carrier Fluid Flowrate or Nozzle Pressure Drop, Dry Scrubber.	Carrier fluid flowrate or pressure drop.	Manuf Spec	10 min
Sorbent Specs, Dry scrubber	Brand and Type	Comp Test	N/A	Same brand and type.
Proposed Option 2 (facility choice)	CEMS	HCl and Cl2 CEMS	CEMS Std	2 hours
Additional Option Factors Affecting Cl2 Formation.	Surrogate CEMS TBD	HCl CEMS Comp Test	Comp Test TBD	2 hours TBD.	Avg over all runs.

Property of interest	Method
Heating Value	EPA 325.3/PARR.
Kinematic Viscosity	ASTM D240.
Flash Point	SW-846 1010.
Total Nitrogen	ASTM D4629.
Total Halogens	EPA 325.3/PARR.
Antimony	SW-846 7040.
Arsenic	SW-846 7060.
Barium	SW-846 7080.
Beryllium	SW-846 7090.
Cadmium	SW-846 7130.
Chromium	SW-846 7190.
Cobalt	SW-846 7200.
Lead	SW-846 7420.
Manganese	SW-846 7460.
Mercury	SW-846 7470.
Nickel	SW-846 7520.
Selenium	SW-846 7740.
Silver	SW-846 7760.
Thallium	SW-846 7840.
Appendix IX Volatile Organics	SW-846 8240.
Appendix IX Semivolatile Organics	SW-846 8270.

Options	Cement kilns	LWA kilns	Commercial incinerators	On-site incinerators
Baseline	$104	$194	$806	$28,500
6 percent Floor	$40	$39	$23	$47
6 percent BTF	50	56	31	57

HAP	Unit	Baseline to 6 percent floor	6 percent floor to 6 percent BTF
D/F	$/g	$12,000	$560,000
Mercury	$/lb	2,600	5,400
LVM	$/Mton	407,000	NA
SVM	$/Mton	315,000	NA
Chlorine	$/Mton	7,000	2,240
Particulate	$/Mton	4,400	3,200
CO	$/Mton	1,360	NA
THC	$/Mton	2,800	NA
Note: NA = Zero incremental reduction in HAP emissions (Dollars divided by zero = NA).

Source category	Dioxin emissions (kg TEQ/year)
Medical Waste Incinerators	5.1
Municipal Waste Incinerators	3.0
Hazardous Waste-burning Incinerators, Cement Kilns, and Lightweight Aggregate Kilns	0.9

Chemical name	Concentration limit (mg/kg at 10,000 BTU/lb)	Maximum detection limit (mg/kg)
Total Nitrogen as N	9.2
Total Halogens as Cl	25
Antimony	(¹)	7.0
Arsenic	(¹)	0.14
Barium	(¹)	14
Beryllium.	(¹)	0.70
Cadmium	(¹)	0.70
Chromium	(¹)	1.4
Cobalt	(¹)	2.8
Lead	(¹)	7.0
Manganese	(¹)	0.70
Mercury	(¹)	0.10
Nickel	(¹)	2.8
Selenium	(¹)	0.14
Silver	(¹)	1.4
Thallium	(¹)	14
a-Naphthylamine	(¹)	670
a,a-Dimethylphenethylamine	(¹)	670
b-Naphthylamine	(¹)	670
1,1-Dichloroethylene	(¹)	34
1,1,2-Trichloroethane	(¹)	34
1,1,2,2-Tetrachloroethane	(¹)	34
1,2-Dibromo-3-chloropropane	(¹)	34
1,2-Dichloroethylene (cis-or trans-)	(¹)	34
1,2,3-Trichloropropane	(¹)	34
1,2,4-Trichlorobenzene	(¹)	670
1,2,4,5-Tetrachlorobenzene	(¹)	670
1,3,5-Trinitrobenzene	(¹)	670
1,4-Dichloro-2-butene (cis-or trans-)	(¹)	34
1,4-Naphthoquinone	(¹)	670
2-Acetylaminofluorene	(¹)	670
2-Chloroethyl vinyl ether	(¹)	34
2-Chloronaphthalene	(¹)	670
2-Chlorophenol	(¹)	670
2-Piccoline	(¹)	670
2,3,4,6-Tetrachlorophenol	(¹)	670
2,4-Dichlorophenol	(¹)	670
2,4-Dimethylphenol	(¹)	670
2,4-Dinitrophenol	(¹)	670
2,4-Dinitrotoluene	(¹)	670
2,4,5-Trichlorophenol	(¹)	670
2,4,6-Trichlorophenol	(¹)	670
2,6-Dichlorophenol	(¹)	670
2,6-Dinitrotoluene	(¹)	670
3-3-Dimethylbenzidine	(¹)	670
3-Methylcholanthrene	(¹)	670
3,3-Dichlorobenzidine	(¹)	670
4-Aminobiphenyl	(¹)	670
4-Bromophenyl phenyl ether	(¹)	670
4,6-Dinitro-o-cresol	(¹)	670
5-Nitro-o-toluidine	(¹)	670
7,12-Dimethylbenz[a]anthracene	(¹)	670
Acetonitrile	(¹)	34
Acetophenone	(¹)	670
Acrolein	(¹)	34
Acrylonitrile	(¹)	34
Allyl chloride	(¹)	34
Aniline	(¹)	670
Aramite	(¹)	670
Benzene	3500
Benzidine	(¹)	670
Benzo [a] anthracene	340
Benzo [a] pyrene	340
Benzo [b] fluoranthene	(¹)	670
Benzo [k] fluoranthene	(¹)	670
Bromoform	(¹)	34
Butyl benzyl phthalate	(¹)	670
Carbon disulfide	(¹)	34
Carbon tetrachloride	(¹)	34
Chlorobenzene	(¹)	34
Chlorobenzilate	(¹)	670
Chloroform	(¹)	34
Chloroprene	(¹)	34
Chrysene	340
cis-1,3-Dichloropropene	(¹)	34
Cresol (o-, m-, or p-)	(¹)	670
Di-n-butyl phthalate	(¹)	670
Di-n-octyl phthalate	340
Diallate	(¹)	670
Dibenzo [a,h] anthracene	340
Dibenz [a,j] acridine	(¹)	670
Dichlorodifluoromethane	(¹)	34
Diethyl phthalate	(¹)	670
Dimethoate	(¹)	670
Dimethyl phthalate	(¹)	670
Dinoseb	(¹)	670
Diphenylamine	(¹)	670
Disulfoton	(¹)	670
Ethyl methacrylate	(¹)	34
Ethyl methanesulfonate	(¹)	670
Famphur	(¹)	670
Fluoranthene	(¹)	670
Fluorene	(¹)	670
Hexachlorobenzene	(¹)	670
Hexachlorobutadiene	(¹)	670
Hexachlorocyclopentadiene	(¹)	670
Hexachloroethane	(¹)	670
Hexachlorophene	(¹)	17000
Hexachloropropene	(¹)	670
Indeno(1,2,3-cd)pyrene	(¹)	670
Isobutyl alcohol	(¹)	34
Isodrin	(¹)	670
Isosafrole	(¹)	670
Kepone	(¹)	1300
m-Dichlorobenzene	(¹)	670
Methacrylonitrile	(¹)	34
Methapyrilene	(¹)	670
Methyl bromide	(¹)	34
Methyl chloride	(¹)	34
Methyl ethyl ketone	(¹)	34
Methyl iodide	(¹)	34
Methyl methacrylate	(¹)	34
Methyl methanesulfonate	(¹)	670
Methyl parathion	(¹)	670
Methylene chloride	(¹)	34
N-Nitrosodi-n-butylamine	(¹)	670
N-Nitrosodiethylamine	(¹)	670
N-Nitrosomethylethylamine	(¹)	670
N-Nitrosomorpholine	(¹)	670
N-Nitrosopiperidine	(¹)	670
N-Nitrosopyrrolidine	(¹)	670
Naphthalene	2800
Nitrobenzene	(¹)	670
o-Dichlorobenzene	(¹)	670
o-Toluidine	(¹)	670
O,O-Diethyl O-pyrazinyl phospho-thioate	(¹)	670
O,O,O-Triethyl phosphorothionate	(¹)	670
p-(Dimethylamino)azobenzene	(¹)	670
p-Chloro-m-cresol	(¹)	670
p-Chloroaniline	(¹)	670
p-Dichlorobenzene	(¹)	670
p-Nitroaniline	(¹)	670
p-Nitrophenol	(¹)	670
p-Phenylenediamine	(¹)	670
Parathion	(¹)	670
Pentachlorobenzene	(¹)	670
Pentachloroethane	(¹)	34
Pentachloronitrobenzene	(¹)	670
Pentachlorophenol	(¹)	670
Phenacetin	(¹)	670
Phenol	(¹)	670
Phorate	(¹)	670
Pronamide	(¹)	670
Pyridine	(¹)	670
Safrole	(¹)	670
Tetrachloroethylene	(¹)	34
Tetraethyldithiopyrophosphate	(¹)	670
Toluene	35000
Trichloroethylene	(¹)	34
Trichlorofluoromethane	(¹)	34
Vinyl Chloride	(¹)	34

Fuel type (physical param)	Gasoline	No. 2	No. 4	No. 6	Comp. 50th	Comp 90th
Flash Point (°C).	< 0	44	66	69	63	< 0
Kinematic viscosity (cSt @ 40 deg.C)		3.7	6.4	660	6.4
Note: Kinematic viscosity for gasoline is less than measureable levels.

Fuel type ²²⁰ (parameter)	Gasoline	No. 2	No. 4	No. 6
Flashpoint (°C)	221-42	38	55	60
Kinematic viscosity (cSt@40°C)	222 0.6	3.4	24	50 (at 100°C)
²²⁰ Fuel oil specifications from ASTM Designation D 396-92, Standard Specifications for Fuel Oils. ²²¹ Felder, M.F., and R.W. Rousseau, Elementary Principles of Chemical Processes, John Wiley and Sons, New York, 1978, 420. ₂₂₂ Perry, Robert H., Don W. Green, and James O. Moloney, Perry's Chemical Engineers' Handbook: Sixth Edition, McGraw-Hill Book Co., New York, 1984, 9-13.

Measurement point	CO low range (ppm)	CO high range (ppm)	O₂ (percent)
1	0-40	0-600	0-2
2	60-80	900-1200	8-10
3	140-160	2100-2400	14-16

Day	Date	Time	Calibration value	Monitor response	Difference	Percent of span (¹)
Zero/low level:
1
2
3
4
5
6
7
High level:
1
2
3
4
5
6
7
1=Acceptance Criteria: ≤3% of span each day for seven days.

Run No.	Calibration value	Monitor response	Difference
Run No.	Calibration value	Monitor response	Zero/Low	Mid	High
1-Zero
2-Mid
3-High
4-Mid
5-Zero
6-High
7-Zero
8-Mid
9-High	Mean Difference =
	Calibration Error =		%	%	%

n^a	t_0.975	n^a	t_0.975	n^a	t_0.975
2	12.706	7	2.447	12	2.201
3	4.303	8	2.365	13	2.179
4	3.182	9	2.306	14	2.160
5	2.776	10	2.262	15	2.145
6	2.571	11	2.228	16	2.131
^a The values in this table are already corrected for n-1 degrees of freedom. Use n equal to the number of individual values.

f	t_f	v_f	n'	un' (75)
7	2.365	1.7972	7	1.233
8	2.306	1.7110	8	1.223
9	2.262	1.6452	9	1.214
10	2.228	1.5931	10	1.208
11	2.201	1.5506	11	1.203
12	2.179	1.5153	12	1.199
13	2.160	1.4854	13	1.195
14	2.145	1.4597	14	1.192
15	2.131	1.4373	15	1.189
16	2.120	1.4176	16	1.187
17	2.110	1.4001	17	1.185
18	2.101	1.3845	18	1.183
19	2.093	1.3704	19	1.181
20	2.086	1.3576	20	1.179
21	2.080	1.3460	21	1.178
22	2.074	1.3353	22	1.177
23	2.069	1.3255	23	1.175
24	2.064	1.3165	24	1.174
25	2.060	1.3081	25	1.173

f	F_ƒ	f	FΦ
1	161.4	16	4.49
2	18.51	17	4.45
3	10.13	18	4.41
4	7.71	19	4.38
5	6.61	20	4.35
6	5.99	22	4.30
7	5.59	24	4.26
8	5.32	26	4.23
9	5.12	28	4.20
10	4.96	30	4.17
11	4.84	40	4.08
12	4.75	50	4.03
13	4.67	60	4.00
14	4.60	80	3.96
15	4.54	100	3.94

Gas	Concentration
Carbon Monoxide	500±50 ppm.
Carbon Dioxide	10±1 percent.
Oxygen	20.9±1 percent.
Sulfur Dioxide	500±50 ppm.
Nitrogen Dioxide	250±25 ppm.
Water Vapor	25±5 percent.
Hydrogen Chloride (HCl)	50±5 ppm.
Chlorine (Cl₂)	10±1 ppm.

Gas	Concentration
Carbon Monoxide	500 ± 50 ppm.
Carbon Dioxide	10 ± 1 percent.
Oxygen	20.9 ± 1 percent.
Sulfur Dioxide	500 ± 50 ppm.
Nitrogen Dioxide	250 ± 25 ppm.
Water Vapor	25 ± 5 percent.
Hydrogen Chloride (HCl)	50 ± 5 ppm.

CEMS	Performance specification
Carbon monoxide	4B
Oxygen	4B
Total hydrocarbons	8A
Mercury, semivolatile metals, and low volatile metals.	10
Particulate matter	11
Mercury	12
Hydrochloric acid (hydrogen chloride)	13
Chlorine gas (diatomic chlorine)	14

Volatiles	Semivolatiles
Benzene	Bis(2-ethylhexyl)phthalate.
Toluene	Naphthalene.
Carbon tetrachloride	Phenol.
Chloroform	Diethyl phthalate.
Methylene chloride	Butyl benzyl phthalate.
Trichloroethylene	2,4-Dimethylphenol.
Tetra chloroethylene	o-Dichlorobenzene.
1,1,1-Trichloroethane	m-Dichlorobenzene.
Chlorobenzene	p-Dichlorobenzene.
cis-1,4-Dichloro-2-butene	Hexachlorobenzene.
Bromochloromethane	2,4,6-Trichlorophenol.
Bromodichloromethane	Fluoranthene.
Bromoform	o-Nitrophenol.
Bromomethane	1,2,4-Trichlorobenzene.
Methylene bromide	o-Chlorophenol.
Methyl ethyl ketone	Pentachlorophenol.
	Pyrene.
	Dimethyl phthalate.
	Mononitrobenzene.
	2,6-Toluene diisocyanate.
	Polychlorinated dibenzo-p-dioxins.
	Polychlorinated dibenzo-furans.

Promulgation date	Title of regulation	Federal Register reference	Effective date
[Insert date of publication of final rule in the Federal Register (FR)]	Combustion Facilities Hazardous Waste numbers	[Insert FR page numbers]	[Insert date of publication of final rule]