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Yes. Empty bulk packagings must be transported in the same manner as when they contained a larger quantity of hazardous materials. If the bulk packagings are not visible in the van trailer then the outside of the vehicle would need placards and ID numbers [see 173.29(a)].
['Hazmat markings, Placards, and Labels', 'Shipping papers - Hazmat']
['Residue: last contained - Hazmat', 'Subsidiary placards - Hazmat']