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Appendix V to 40 CFR 265 lists examples of incompatible wastes as well as the potential consequences of mixing them. Note that the lists in this table do not cover every waste or every situation! Owners and operators must properly analyze and identify hazardous wastes at facilities to avoid creating hazards to employees and the environment.
In the lists below, the mixing of a Group A material with a Group B material may have the potential consequences noted at the bottom of each list.
Group 1-A | Group 1-B |
Acetylene sludge | Acid sludge |
Alkaline caustic liquids | Acid and water |
Alkaline cleaner | Battery acid |
Alkaline corrosive liquids | Chemical cleaners |
Alkaline corrosive battery fluid | Electrolyte, acid |
Caustic wastewater | Etching acid liquid or solvent |
Lime sludge and other corrosive alkalies | |
Lime wastewater | Pickling liquor and other corrosive acids |
Lime and water | Spent acid |
Spent caustic | Spent mixed acid |
Spent sulfuric acid | |
Potential consequences: Heat generation; violent reaction. |
Group 2-A | Group 2-B |
Aluminum | Any waste in Group 1-A or 1-B |
Beryllium | |
Calcium | |
Lithium | |
Magnesium | |
Potassium | |
Sodium | |
Zinc powder | |
Other reactive metals and metal hydrides | |
Potential consequences: Fire or explosion; generation of flammable hydrogen gas. |
Group 3-A | Group 3-B |
Alcohols | Any concentrated waste in Groups 1-A or 1-B |
Water | Calcium |
Lithium | |
Metal hydrides | |
Potassium | |
SO2Cl2, SOCl2, PCl3, CH3SiCl3 | |
Other water-reactive waste | |
Potential consequences: Fire, explosion, or heat generation; generation of flammable or toxic gases. |
Group 4-A | Group 4-B |
Alcohols | Concentrated Group 1-A or 1-B wastes |
Aldehydes | Group 2-A wastes |
Halogenated hydrocarbons | |
Nitrated hydrocarbons | |
Unsaturated hydrocarbons | |
Other reactive organic compounds and solvents | |
Potential consequences: Fire, explosion, or violent reaction. |
Group 5-A | Group 5-B |
Spent cyanide and sulfide solutions | Group 1-B wastes |
Potential consequences: Generation of toxic hydrogen cyanide or hydrogen sulfide gas. |
Group 6-A | Group 6-B |
Chlorates | Acetic acid and other organic acids |
Chlorine | Concentrated mineral acids |
Chlorites | Group 2-A wastes |
Chromic acid | Group 4-A wastes |
Hyphochlorites | Other flammable and combustible wastes |
Nitrates | |
Nitric acid, fuming | |
Perchlorates | |
Permanganates | |
Peroxides | |
Other strong oxidizers | |
Potential consequences: Fire, explosion, or violent reaction. |
Appendix V to 40 CFR 265 lists examples of incompatible wastes as well as the potential consequences of mixing them. Note that the lists in this table do not cover every waste or every situation! Owners and operators must properly analyze and identify hazardous wastes at facilities to avoid creating hazards to employees and the environment.
In the lists below, the mixing of a Group A material with a Group B material may have the potential consequences noted at the bottom of each list.
Group 1-A | Group 1-B |
Acetylene sludge | Acid sludge |
Alkaline caustic liquids | Acid and water |
Alkaline cleaner | Battery acid |
Alkaline corrosive liquids | Chemical cleaners |
Alkaline corrosive battery fluid | Electrolyte, acid |
Caustic wastewater | Etching acid liquid or solvent |
Lime sludge and other corrosive alkalies | |
Lime wastewater | Pickling liquor and other corrosive acids |
Lime and water | Spent acid |
Spent caustic | Spent mixed acid |
Spent sulfuric acid | |
Potential consequences: Heat generation; violent reaction. |
Group 2-A | Group 2-B |
Aluminum | Any waste in Group 1-A or 1-B |
Beryllium | |
Calcium | |
Lithium | |
Magnesium | |
Potassium | |
Sodium | |
Zinc powder | |
Other reactive metals and metal hydrides | |
Potential consequences: Fire or explosion; generation of flammable hydrogen gas. |
Group 3-A | Group 3-B |
Alcohols | Any concentrated waste in Groups 1-A or 1-B |
Water | Calcium |
Lithium | |
Metal hydrides | |
Potassium | |
SO2Cl2, SOCl2, PCl3, CH3SiCl3 | |
Other water-reactive waste | |
Potential consequences: Fire, explosion, or heat generation; generation of flammable or toxic gases. |
Group 4-A | Group 4-B |
Alcohols | Concentrated Group 1-A or 1-B wastes |
Aldehydes | Group 2-A wastes |
Halogenated hydrocarbons | |
Nitrated hydrocarbons | |
Unsaturated hydrocarbons | |
Other reactive organic compounds and solvents | |
Potential consequences: Fire, explosion, or violent reaction. |
Group 5-A | Group 5-B |
Spent cyanide and sulfide solutions | Group 1-B wastes |
Potential consequences: Generation of toxic hydrogen cyanide or hydrogen sulfide gas. |
Group 6-A | Group 6-B |
Chlorates | Acetic acid and other organic acids |
Chlorine | Concentrated mineral acids |
Chlorites | Group 2-A wastes |
Chromic acid | Group 4-A wastes |
Hyphochlorites | Other flammable and combustible wastes |
Nitrates | |
Nitric acid, fuming | |
Perchlorates | |
Permanganates | |
Peroxides | |
Other strong oxidizers | |
Potential consequences: Fire, explosion, or violent reaction. |