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Hazmat markings provide important information about the contents of a packaging, freight container, or transport vehicle and help warn of hazards posed by that material. Labels are printed on or affixed to packages containing hazardous materials. Color- and symbol-coded, labels provide easy and immediate warning of the hazardous materials inside a package. Hazardous materials placards correspond closely with the shape, color, and design of hazardous labels but are much larger than labels.
Markings provide important information about the contents of a packaging, freight container, or transport vehicle and help warn of hazards posed by that material during transport. The markings give additional information, not provided by labels or placards, about the hazardous material in a package or vehicle.
Labels are printed on or affixed to packages containing hazardous materials. Color- and symbol-coded, labels provide easy and immediate warning of the hazardous materials inside a package. The Hazardous Materials Regulations (HMR) have specific requirements for design, use, placement, prohibitions, and exceptions for labels.
Hazardous materials placards correspond closely with the shape, color, and design of hazardous materials labels. However, placards are much larger than labels. Placards alert people to potential dangers associated with particular hazardous materials contained in motor vehicles, rail cars, freight containers, cargo tanks, and portable tanks.
Specific definitions for terms associated with markings, placards, and labels clarify their meaning.
Definitions for markings terminology
Bulk packagings: Other than vessels or barges, and including transport vehicles or freight containers, are bulk packagings in which hazardous materials are loaded with no intermediate form of containment and that have:
A large packaging in which hazardous materials are loaded with an intermediate form of containment, such as one or more articles or inner packagings, is also a bulk packaging.
Cargo aircraft only: This aircraft is used to transport cargo and is not engaged in carrying passengers. The terms “cargo aircraft only,” “cargo-only aircraft,” and “cargo aircraft” have the same meaning.
Limited quantity: When specified as such in a section applicable to a particular material, it means the maximum amount of a hazardous material for which there is a specific labeling or packaging exception.
Marking: This consists of a descriptive name, identification number, instructions, cautions, weight, specifications, or United Nations (UN) marks, or combinations thereof, required by the Hazardous Materials Regulations (HMR) on outer packagings of hazardous materials.
Non-bulk packagings: These packagings have:
Technical name: This is a recognized chemical name or microbiological name currently used in scientific and technical handbooks, journals, and texts. Generic descriptions are authorized for use as technical names provided they readily identify the general chemical group or microbiological group. Examples of acceptable generic chemical descriptions are organic phosphate compounds, petroleum aliphatic hydrocarbons, and tertiary amines. For proficiency testing only, generic microbiological descriptions such as bacteria, mycobacteria, fungus, and viral samples may be used. Except for names that appear in Subpart B of Part 172 of this subchapter, trade names may not be used as technical names.
Definitions associated with placards
Freight container: A reusable container having a volume of 64 cubic feet or more, designed and constructed to permit being lifted with its contents intact and intended primarily for containment of packages (in unit form) during transportation.
Rail car: A car designed to carry freight or non-passenger personnel by rail, and includes a box car, flat car, gondola car, hopper car, tank car, and occupied caboose.
Residue: The hazardous material remaining in a packaging, including a tank car, after its contents have been unloaded to the maximum extent practicable and before the packaging is either refilled or cleaned of hazardous material and purged to remove any hazardous vapors.
Subsidiary hazard: The hazard of a material other than the primary hazard.
Transport vehicle: A cargo-carrying vehicle such as an automobile, van, tractor, truck, semitrailer, tank car, or rail car used for transportation of cargo by any mode. Each cargo-carrying body (trailer, rail car, etc.) is a separate transport vehicle.
Unit load device: Any type of freight container, aircraft container, aircraft pallet with a net, or aircraft pallet with a net over an igloo.
Definitions of terms associated with labels
Dewar flask: An insulating storage vessel that greatly lengthens the time during which its contents remain hotter or cooler than the flask’s surroundings. The vacuum flask consists of two flasks, placed one within the other and joined at the neck. The gap between the two flasks is partially evacuated of air, creating a near-vacuum that significantly reduces heat transfer by conduction or convection.
Limited quantity: When specified as such in a section applicable to a particular material, it means the maximum amount of a hazardous material for which there is a specific labeling or packaging exception.
Overpack: An enclosure used by a single consignor to provide protection or convenience in handling a package or to consolidate two or more packages. Overpack does not include a transport vehicle, freight container, or aircraft unit load device.
Examples of overpacks are one or more packages:
Primary label: A hazard warning label that corresponds with the primary hazard of the material.
Subsidiary label: A hazard warning label that corresponds with the subsidiary hazard of the material.
Markings provide important information about the contents of a packaging, freight container, or transport vehicle and help warn of hazards posed by that material during transport. Markings give additional information, not provided by labels or placards, about the hazardous material in a package or vehicle.
Who is responsible for markings?
Marking requirements apply to non-bulk and bulk packagings transported by rail, air, vessel, and highway. Certain requirements specifically apply to transport vehicles and freight containers.
The individual who prepares non-bulk packages of hazardous material for transport is responsible for marking the package. This responsibility includes:
In most cases, the responsibility for marking bulk packagings, freight containers, and transport vehicles rests with the individual initiating the shipment. The carrier is responsible for replacing identification number markings that are lost, damaged, or destroyed during transit.
Types of markings that are prohibited
No packaging may be marked with a proper shipping name or identification number unless the packaging contains the identified material or its residue.
Specifications for markings
To withstand conditions normally encountered during transportation, all markings must be:
Manufacturer/specification packaging marking (178.503)
Most authorized packagings for hazardous materials must be marked with a United Nations (UN) packaging marking (for non-bulk packaging) or a specification packaging marking (such as DOT 406). For more information on these markings, refer to the Markings section under packaging definitions.
Most non-bulk packagings must be marked with the following information:
Description/proper shipping name (172.308)
The description/proper shipping name as shown in Column (2) of the Hazardous Materials Table must be marked on the non-bulk package.
Abbreviations are usually not allowed in a proper shipping name marking. The only exception includes abbreviations appearing as part of the authorized description in Column (2) of the Hazardous Materials Table, such as “TNT” or “PCB”.
Technical names (172.301)
Any package that contains hazardous materials described by a proper shipping name preceded by the symbol “G” in Column (1) of the Hazardous Materials Table must be marked with the technical name in parentheses in association with the proper shipping name. However, a technical name should not be marked on the outer package of a Division 6.2 material.
Identification number (172.301)
The identification number shown in Column (3) of the Hazardous Materials Table, for the description/proper shipping name being used, must be marked on the package. The appropriate “UN” “NA,” or “ID” prefix must be included.
Identification numbers marked on non-bulk packagings must meet specific size requirements. The identification numbers must be at least 0.47 inches (12 mm) high. On smaller packages — 8 gallons (30 L) or less, 66 pounds (30 kg) maximum, or cylinders with a water capacity of 16 gallons (60 L) or less — the identification numbers must be at least 0.24 inches (6 mm) high. For even smaller packages, capacity of 1.32 gallons (5 L) or 11 pounds (5 kg) or less, the size of the identification numbers must be appropriate for the package size.
Name and address (172.301)
The name and address of the consignee (receiver/buyer) or consignor (shipper/seller) must be marked on the package unless:
Special permit packagings (172.302)
The special permit number is required to be plainly and durably marked on the packaging if it is authorized for use under a special permit. The package should be marked “DOT-SP (followed by the special permit number).”
Hazardous substances (172.324)
Non-bulk packagings that contain a reportable quantity (RQ) of a hazardous substance must be marked with the letters “RQ” in association with the proper shipping name.
PCBs (761.40, 761.45)
Polychlorinated biphenyls (PCBs) are hazard substances that must be transported in compliance with the Hazardous Materials Regulations (HMR) and special additional requirements of the U.S. Environmental Protection Agency (EPA).
The HMR require the proper shipping name, identification number, and RQ to be marked on each non-bulk package.
EPA regulations require the package to be marked with the PCB mark and a minimum size 6 x 6 inches (152.4 mm x 152.4 mm). This PCB mark may be reduced proportionately to a minimum of 2 x 2 inches (50.8 mm x 50.8 mm) to fit on PCB articles or equipment.
An even smaller rectangular PCB mark may be used on small packages. This small rectangular PCB mark may be proportionately reduced to a minimum of 0.4 x 0.8 inches (10.16 mm x 20.32 mm) to fit on PCB articles or equipment.
EPA regulations also require a vehicle to be marked on each side and each end with this marking, if transporting PCB containers that contain more than 99.4 pounds (45 kg) of liquid PCBs in concentrations of 50 to 500 ppm.
Large quantities of non-bulk packages
A transport vehicle or freight container loaded with only a single hazardous material in non-bulk packages must be marked, on each side and each end with the identification number specified for the material, subject to the following:
The above requirement does not apply to Class 1 materials, Class 7 materials, or non-bulk packagings for which identification numbers are not required, such as limited quantity materials.
Large quantities of non-bulk inhalation hazards
A transport vehicle or freight container loaded at one loading facility with 2,205 pounds (1,000 kg) or more of non-bulk packages containing a material poisonous by inhalation (in Hazard Zone A or B), having the same shipping name and identification number, must be marked with the identification number specified for the material, on each side and each end.
If the transport vehicle or freight container contains more than one inhalation hazard material that meets the above identification number marking requirement, it must be marked with the identification number for only one material. That one identification number is determined by the following:
Unless specifically excepted, all bulk packagings of hazardous materials must be marked with the identification number(s) of the contents. These numbers, unless otherwise provided, must be marked:
Identification number display
There are three ways in which identification numbers may be displayed:
If the identification number markings on a portable tank or cargo tank are not visible, the transport vehicle or freight container used to transport the tank must also be marked with the numbers, on each side and each end.
When a tank is permanently installed within an enclosed cargo body of a transport vehicle or freight container, the identification number marking need only be displayed on the sides and ends of the tank that are visible when the enclosed cargo body is opened or entered.
Identification numbers are not required on the ends of portable tanks and cargo tanks having more than one compartment if hazardous materials having different identification numbers are transported in the compartments. The identification numbers on the sides of the tank must be displayed in the same sequence as the compartments containing the materials they identify.
Special permit packaging
When a bulk packaging is labeled instead of placarded, the identification number markings may be displayed on the bulk packaging in the same manner as would be required for a non-bulk packaging.
DOT-SP (followed by the special permit number) is required to be marked on the packaging if it is authorized for use under a special permit.
Portable tanks
In addition to displaying the applicable identification number, portable tanks must be marked with:
IBCs
When an intermediate bulk container (IBC) is labeled instead of placarded, the IBC may display the proper shipping name and identification number markings as required by 172.301(a)(1) for non-bulk packagings. These smaller markings may be used in place of the identification number marking on an orange panel, placard, or white square-on-point configuration.
Cargo tanks
In addition to the identification number, cargo tanks (except for certain nurse tanks) that are used to transport gases (Class 2 material) must be marked on each side and each end with the proper shipping name or appropriate common name of the gas.
Each specification cargo tank that successfully completes a test/inspection must be marked with the date (month and year) and the type of test/inspection completed. This marking must be displayed near the specification plate or anywhere on the front head. The type of test/inspection may be abbreviated as follows:
Tank cars
In addition to the identification number, tank cars — when required by a special provision to the Hazardous Materials Table or by 172.330 — must be marked on each side with the proper shipping name or appropriate common name.
In addition to the identification number marking, multi-unit tank car tanks must be marked on two opposing sides with the proper shipping name or appropriate common name.
If the proper shipping name for a hazardous material in a bulk packaging has been changed, the bulk packaging may not need to be remarked if:
A bulk packaging used to transport petroleum crude oil containing hydrogen sulfide (sour crude oil) in sufficient concentrations that the vapors may present an inhalation hazard must be marked with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) toxic pictogram or a warning statement such as “Danger: Possible Hydrogen Sulfide Inhalation Hazard.” The marking must be displayed at each location (manhole, loading head) where exposure to hydrogen sulfide vapors may occur.
A package containing a limited quantity of hazardous materials is required to be marked with one of the following:
The width of the border forming the square-on-point marking must be at least 0.08 inches (2 mm). Each side of the marking must be at least 3.94 inches (100 mm). If the package size requires a reduced size marking, then each side of the marking may be reduced to no less than 1.97 inches (50 mm). For cargo transport units transported by water, each side of the marking must have a minimum size of 9.84 inches (250 mm).
Additional markings may be required depending on the hazardous material being transported or the type of package used.
Hazardous wastes
Proper shipping names marked on non-bulk packages of hazardous waste are not required to include the word “waste” if the U.S. Environmental Protection Agency (EPA) marking is displayed in accordance with 40 CFR Section 262.32.
Orientation arrow markings
Combination packagings that have inner packagings containing liquid hazardous materials, single packaging fitted with vents, or open cryogenic receptacles must be marked with orientation arrows. These arrows must be displayed on two opposite vertical sides of the packaging — with the arrows pointing in the correct upward direction.
Orientation arrows are not required on packages that contain:
Inhalation hazards
Packagings that contain materials poisonous-by-inhalation must be marked “INHALATION HAZARD” in association with required labels or placards or the proper shipping name. The “INHALATION HAZARD” marking is not required if the package bears a poison gas or poison inhalation hazard label (or placard) displaying the words “INHALATION HAZARD.”
This marking on bulk packages must be on two opposite sides and have:
Poisons
Non-bulk plastic outer packagings used as single or composite packagings for Division 6.1 materials must be permanently marked with the word “POISON” — either by embossing or other durable means. This marking must be at least 0.25 inches (6.3 mm) in height and located within 6 inches (150 mm) of the closure of the packaging.
A package containing a Division 6.1 (poison) material in Packing Group III may be marked “PG III” adjacent to the “POISON” label.
Keep away from heat (172.(317)
For transportation by aircraft, packages containing self-reactive substances of Division 4.1 or organic peroxides of Division 5.2 must be marked with the “KEEP AWAY FROM HEAT” handling mark. This marking must be at least 4.1 inches (105 mm) in height and 2.9 inches (74 mm) in width.
Explosive materials (172.320)
A package of Class 1 material must be marked with the EX-number for each substance, article, or device contained therein unless it is excepted from this marking as specified in 172.320. In some situations, no marking is required; for others, a national stock number or product code may be used.
When more than five different Class 1 materials are packed in the same package, no more than five of the numbers, codes, or a combination thereof are required to be marked on the package.
Marine pollutants
Non-bulk packagings that contain marine pollutants and are offered for transportation by vessel must be marked with:
The marine pollutant marking is not required on single packagings or combination packagings where each single package or each inner packaging of combination packagings has:
The marine pollutant marking is not required on a combination packaging containing a marine pollutant (other than a severe marine pollutant) in inner packagings, each of which contains:
Non-bulk packagings of marine pollutants transported by motor vehicle, rail car, or aircraft are not subject to marine pollutant requirements.
Bulk packagings with a capacity of 1,000 gallons (3,785 L) or more and that contain marine pollutants must be marked on each side and each end with the marine pollutant marking. A bulk packaging with a capacity of less than 1,000 gallons (3,785 L) must be marked on two opposing sides or ends with the marine pollutant marking.
Did you know?
Except for transportation by vessel, a bulk packaging, freight container, or transport vehicle that bears a label or placard is not required to display the marine pollutant marking.
A package of limited quantity material that is marked with a square-on-point limited quantity marking is not required to display the marine pollutant marking.
The symbol and border must be black on a white background, or be of a contrasting color to the surface on which the marking is displayed. The width of the border must be at least 0.08 inches (2 mm). Each side of the marking must be at least 3.9 inches (100 mm) for non-bulk packages and bulk packages with a capacity of less than 1,000 gallons (3,785 L). For all other bulk packages, each side of the marking must be at least 9.8 inches (250 mm).
Elevated-temperature materials
Most bulk packages that contain an elevated-temperature material must be marked on two opposing sides with the word “HOT” — in black or white Gothic lettering on a contrasting background. This marking must be displayed on the packaging itself or in black lettering on a white square-on-point configuration that is the same size as a placard.
Bulk packages that contain molten aluminum or molten sulfur must be marked “MOLTEN ALUMINUM” or “MOLTEN SULFUR” as appropriate, instead of with the word “HOT.
For bulk packages that must be marked “HOT,” “MOLTEN ALUMINUM,” or “MOLTEN SULFUR,” the letters must be at least:
The Hazardous Materials Regulations (HMR) allow the “HOT” marking and identification number marking to be combined on the same white square-on-point configuration. In this case, the identification number must be displayed in the center of the white square-on-point configuration, and the word “HOT” must be displayed in the upper corner. The word “HOT” must be in black letters having a height of at least 2 inches (50 mm).
Radioactive materials (172.310)
Each package containing Class 7 (radioactive) materials must also be marked with:
Regulated medical waste (172.323)
A bulk packaging containing a regulated medical waste must be marked with the “BIOHAZARD” marking, visible from the direction it faces:
The “BIOHAZARD” marking must be at least 6 inches (152.4 mm) on each side. This marking may be displayed on a white square-on-point configuration.
Non-odorized LPG (172.301, 172.326, 172.328, 172.330)
No person may offer or transport certain specification cylinders, a portable tank, cargo tank, or tank car containing liquefied petroleum gas (LPG) that is not odorized unless the words “NON-ODORIZED” or “NOT ODORIZED” appear near the proper shipping name. This marking must appear on two opposing sides on portable tanks, cargo tanks, and tank cars.
Overpacks
Each overpack:
Fumigant marking
Each truck body or trailer, rail car, or freight container containing lading that has been fumigated or treated with any material, or is undergoing fumigation, must have a “FUMIGANT” marking displayed so it can be seen by any person attempting to enter the vehicle or container.
The printing on the “FUMIGANT” marking must be black on a white background. The size of the white background must be at least 15.75 inches (400 mm) wide and at least 11.8 inches (300 mm) high. The width of the border must be at least 0.08 inches (2 mm). Text on this marking must be at least 0.98 inches (25 mm). The technical name of the fumigant must be entered in the appropriate place (*) on the marking.
The “FUMIGANT” marking must be displayed until the truck body or trailer, rail car, or freight container has been completely ventilated.
Reverse logistics
Reverse logistics is the offering or transporting of goods by motor vehicle from a retail store for return to the manufacturer, supplier, or distribution facility for the purpose of capturing value (credit), recall, replacement, recycling, or similar reason. This does not include hazardous waste.
Materials involved in reverse logistics are excepted from many of the Hazardous Materials Regulations (HMR). However, shipments of reverse logistics materials must be marked with the limited quantity marking or the words “REVERSE LOGISTICS – HIGHWAY TRANSPORT ONLY – UNDER 49 CFR 173.157.”
Small quantities (173.4)
When transported by highway or rail only, packages containing small quantities of materials meeting the requirements in Section 173.4 must be marked with the statement “This package conforms to 49 CFR 173.4 for domestic highway or rail transport only.”
Excepted quantities (173.4a)
When transported by air or vessel only, packages containing excepted quantities of materials meeting the requirements in Section 173.4a must be marked with the excepted quantities marking. The “*” must be replaced with the hazard class or division of each hazardous material in the package. The “**” must be replaced with the name of the shipper or consignee, if not shown elsewhere on the package. The hatching must be the same color, black or red on a contrasting background. The marking must be 3.9 inches (100 mm) by 3.9 inches (100 mm).
Hazardous materials placards correspond closely with the shape, color, and design of hazardous materials labels. However, placards are much larger than labels. Placards alert persons to potential dangers associated with the particular hazardous material contained in a motor vehicle, rail car, freight container, cargo tank, or portable tank.
Anyone offering or accepting hazardous materials for shipment in an amount that requires placards must ensure the material is placarded according to applicable sections of the Hazardous Materials Regulations (HMR).
Placarding requirements apply to each person who offers for transport or transports hazardous materials. The placarding requirements do not apply to the following materials:
Placards are used to identify the hazard or hazards of materials contained in bulk packagings, freight containers, unit load devices, transport vehicles, or rail cars.
Responsibility
The responsibility for affixing or supplying placards varies according to mode of transport and type of packaging used to transport the hazardous material.
For highway transport, the shipper is responsible for providing the appropriate placards to the driver. The driver is responsible for applying them correctly on the vehicle and maintaining them during transport. In addition, drivers are responsible for any placarding necessitated by aggregate shipments.
Bulk packagings (172.514)
The person who offers a bulk packaging containing a hazardous material for transportation is required to affix the required placards before or at the time the packaging is offered for transportation.
Freight containers and aircraft unit load devices (172.512)
Each person who offers for transportation and each person who loads and transports a hazardous material in a freight container or aircraft unit load device is required to affix the appropriate placards.
Transport vehicles (172.506, 177.823)
When a hazardous material is offered for transport by highway, the individual offering the material must provide the carrier with the required placards — before or at the same time the material is offered for transport — unless the appropriate placards are already affixed to the vehicle.
Typically, the carrier is forbidden from moving the vehicle until placards have been affixed. However, the carrier may move the vehicle before placarding in an emergency situation or when one of the following three conditions are met:
Rail cars (172.508)
When a hazardous material is offered for transport by rail, the individual offering the material must affix the required placard(s) to the rail car — unless the car is already properly placarded. The rail carrier may not accept a rail car for transport unless required placards are affixed.
Prohibited placarding (172.502)
No person may affix a placard to a packaging, freight container, unit load device, motor vehicle, or rail car unless the material being offered for transportation is a hazardous material, the placard applied represents the hazard of the material being offered, and placards conform to requirements in the Hazardous Materials Regulations (HMR).
Signs, advertisements, slogans (such as “Drive Safely”), or other devices that could be confused with a prescribed placard are prohibited.
Permissive placarding (172.502)
Placards may be displayed for a hazardous material, even when not required, if the hazardous material is present and the placarding conforms to regulations.
A bulk packaging, freight container, unit load device, transport vehicle, or rail car placarded according to Canada’s Transport Dangerous Goods (TDG) Regulations, the International Maritime Dangerous Goods (IMDG) Code, or the United Nations (UN) Recommendations is allowed.
Placarding tables (172.504)
Placarding requirements vary according to the category of material (hazard class, division, packing group, or description) being transported and type of packaging (bulk or non-bulk) containing the material. Each bulk packaging, freight container, unit load device, transport vehicle, or rail car containing hazardous material must be placarded on each side and each end (with some exceptions) with the type of placards specified in Table 1 or Table 2 of Section 172.504.
To determine what placards are required, one must know:
The most dangerous categories of hazardous materials are shown in Table 1 of 172.504. Any quantity of material falling within the categories listed in Table 1 must be placarded.
The remaining hazard categories are assigned to Table 2. Any quantity of these materials also must be placarded, but the regulations provide some exceptions under certain conditions.
Less than 1,001 pounds of Table 2 materials
A transport vehicle or freight container that contains less than 1,001 pounds (454 kg) aggregate gross weight of hazardous materials in non-bulk packages covered by Table 2 is not required to display placards. This exception does not apply to bulk packages or materials with subsidiary hazards that must be placarded according to 172.505.
Did you know?
A Class 9 placard is not required for domestic transportation. However, a bulk packaging must be marked with the appropriate identification number as required by the Hazardous Materials Regulations (HMR).
If a transport vehicle, rail car, freight container, or unit load device contains non-bulk packagings of two or more categories of Table 2 materials, the “DANGEROUS” placard may be displayed instead of the separate placards specified in Table 2.
When 2,205 pounds (1,000 kg) or more of one hazard category is loaded at one facility on one vehicle, rail car, freight container, or unit load device, the “DANGEROUS” placard cannot be used for that one hazard category; instead, the placard specified in Table 2 must be displayed.
If three or more different categories of Table 2 materials are in one vehicle, rail car, freight container, or unit load device, and one material is over the 2,205-lb (1,000-kg) limit and requires an individual class placard, the “DANGEROUS” placard may still be used for the other categories of Table 2 material that fall below the 2,205-lb (1,000-kg) limit.
Placard exceptions by hazard class
Class 1 (172.504)
When more than one division placard is required for Class 1 materials on a transport vehicle, rail car, freight container, or unit load device, only the placard representing the lowest division number must be displayed.
The “EXPLOSIVES” 1.4 placard is not required for those Division 1.4 Compatibility Group S (1.4S) materials that are not required to be labeled 1.4S.
For shipments of Class 1 (explosive) materials by aircraft or vessel, the applicable compatibility group letter must be displayed on the required placards.
Gases (172.504)
A “NON-FLAMMABLE GAS” placard is not required on a motor vehicle containing a non-flammable gas if the vehicle contains flammable gas or oxygen and is placarded “FLAMMABLE GAS” or “OXYGEN,” as required.
The “OXYGEN” placard may be used for domestic shipments of oxygen, compressed or oxygen, refrigerated liquid in place of a “NON-FLAMMABLE GAS” placard.
Flammables (172.504)
A “COMBUSTIBLE” placard is not required on a cargo tank, portable tank, or compartmented tank car containing both flammable and combustible liquids when placarded “FLAMMABLE.”
Oxidizers (172.504)
“OXIDIZER” placards are not required for Division 5.1 materials on freight containers, unit load devices, transport vehicles, or rail cars that also contain Division 1.1 or 1.2 materials and are placarded with “EXPLOSIVES” 1.1 or 1.2 placards, as required.
For transportation by transport vehicle or rail car only: An “OXIDIZER” placard is not required for Division 5.1 materials on a transport vehicle, rail car, or freight container that also contains Division 1.5 materials and is placarded with “EXPLOSIVES” 1.5 placards, as required.
Poisons (172.504)
For domestic transportation:
For Division 6.1, Packing Group III materials, a “POISON” placard may be modified to display the text “PG III” below the midline of the placard in place of the word “POISON.”
Class 9 (172.504)
Class 9 placards are not required for domestic transportation.
Freight containers/unit load devices and placards for rail (172.512)
A motor vehicle transporting freight containers or aircraft unit load devices that are not required to be placarded is not required to display placards.
Freight containers and unit load devices being transported for delivery to a consignee immediately after an air or water shipment are also allowed to use the exception for less than 1,001 pounds (454 kg) of Table 2 materials.
A freight container or aircraft unit load device that is only transported by air and is prepared according to Part 7, Chapter 2, Section 2.8 of the International Civil Aviation Organization (ICAO) Technical Instructions is not required to be placarded.
Rail (172.504)
A rail car loaded with a transport vehicle or freight container that is not required to be placarded is not required to display placards.
Primary and subsidiary placards
There are two types of placards:
Generally, only primary placards are displayed. Section 172.505 of the Hazardous Materials Regulations (HMR) requires additional placards to be displayed under certain conditions for several subsidiary hazards. This includes “POISON GAS,” “POISON INHALATION HAZARD,” “POISON,” “CORROSIVE,” and “DANGEROUS WHEN WET.” Other subsidiary placards are permitted to be displayed but are not required.
Placard specifications
To be in compliance, all placards must meet the following specifications:
Tagboard placards must:
White square background
Transportation by highway (172.507)
A square background behind the placard is required when a motor vehicle is used to transport a highway route-controlled quantity of radioactive material.
Placard placement (172.516)
Each placard affixed to a motor vehicle or rail car must be readily visible from the direction it faces — except from the direction of another vehicle or rail car to which the vehicle or rail car is coupled.
The placard placement for the front of a vehicle may be on the front of the truck-tractor instead of, or in addition to, the placard on the front of the cargo-carrying body (e.g., trailer or semitrailer).
Best practice
Most carriers place the front placard on the front of the tractor to make it easier for the driver to change or remove the placard if necessary.
Placards displayed on freight containers or portable tanks loaded on (not enclosed in) a motor vehicle or rail car may be used to meet placarding requirements for the motor vehicle or rail car.
In addition, each placard on a transport vehicle, bulk packaging, unit load device, or freight container must be:
Bulk packagings (172.514)
In most situations, a bulk packaging containing hazardous materials that requires placards must be placarded on each side and each end. Each bulk packaging that previously contained a hazardous material requiring placards must remain placarded when emptied unless it:
The following bulk packagings may be placarded on only two opposite sides or may be labeled instead of placarded:
Flexible bulk containers may be placarded in two opposing positions.
Freight containers and aircraft unit load devices (172.512)
A freight container or aircraft unit load device with a capacity less than 640 cubic feet (18 m3) is required to display one placard as specified in Section 172.504. This requirement does not apply if the freight container or unit load device:
Freight containers with a capacity of less than 640 cubic feet that are not transported by air do not have to be placarded — they may be labeled instead.
Labels are printed on or affixed to packages containing hazardous materials. Labels are color- and symbol-coded to provide easy and immediate warning of hazardous materials inside the package. The Hazardous Materials Regulations (HMR) have specific requirements for design, use, placement, prohibitions, and exceptions for labels.
Labeling requirements apply primarily to non-bulk packagings. The following must also display labels if they are not placarded:
Who is responsible for labeling, and what are the requirements?
Anyone offering or accepting a hazardous material for shipment must ensure the package is labeled according to applicable sections of the HMR.
Once a material has been classified and a proper shipping name has been selected, determining the appropriate labels is a fairly easy process:
Except for the 6.1 label code, the label codes are the same as the hazard classes or divisions, and only one label is possible. For example, a 2.3 label code is a 2.3 (poison gas) label, a 3 label code is a Class 3 (flammable liquid) label, and a 5.1 label code is a 5.1 (oxidizer) label.
For the 6.1 label code, there are two possible labels. If the material has an inhalation hazard, Zone A or B, a “Poison Inhalation Hazard” label is required. If the material does not have an inhalation hazard, Zone A or B, a “Poison” label is required.
Each package containing a hazardous material must be labeled with the label(s) prescribed in Column (6) of the Hazardous Materials Table.
If the material has more than one hazard, all applicable subsidiary labels may not be listed in the table, such as generic or not otherwise specified (n.o.s.) shipping names. If this is the case, subsidiary labels must be determined according to 172.402.
A Division 6.1 subsidiary label is not required on a package containing a Class 8 material that has a subsidiary hazard of Division 6.1 if toxicity of the material is based solely on corrosive destruction of tissue rather than systemic poisoning. Also, a Division 4.1 subsidiary label is not required on a package bearing a Division 4.2 label.
Exceptions (49 CFR 172.400a)
Not all non-bulk packages of hazardous materials will require labels. Labels are not required on the following:
Limited quantities
There are also exceptions to labeling for limited quantities in the following sections:
Types of labels that are prohibited
No package may display a hazardous material warning label unless the package contains the hazardous material and the label represents the hazard of the material in the package.
Packages may not be offered for transportation or transported with a marking or label that could be confused with or conflicts with the required labels unless the package is labeled in conformance with:
Did you know?
Occupational Safety and Health Administration (OSHA) pictograms look similar to U.S. Department of Transportation (DOT) hazard warning labels. In fact, many pictograms and labels share the same images.
Placement
A label on a package of hazardous materials must be clearly visible and not obscured by markings or attachments. Each label must be printed on or affixed to a background of contrasting color, or must have a dotted or solid-line outer border.
The label must be printed on or affixed to a surface (other than the bottom) of the package containing the hazardous material. If possible, the label should be located on the same surface of the package and near the proper shipping name marking.
However, a label may be printed on or placed on a securely affixed tag, or may be affixed by other suitable means to:
When primary and subsidiary labels are required, they must be displayed next to each other, within 6 inches (152.4 mm) of one another. Except as discussed in the section on using duplicate labels, duplicate labeling is not required on a package. This means that only one of each different required label would have to be on the package.
Using duplicate labels
Generally, only one of each different required label must be displayed on a package. However, duplicate labels must be displayed on at least two sides or two ends (other than the bottom) of the following:
Labeling consolidated packages
When two or more packages containing compatible hazardous materials are placed within the same outside container or overpack, the outside container or overpack must be labeled for each class of material contained within, unless labels on the inside packages are visible and represent each hazardous material in the container or overpack.
Label specifications
Labels must meet the following specifications:
Hazard class or division numbers must be displayed in the lower (bottom) corner of primary and subsidiary labels.
Label modifications
Text is not required on a primary or subsidiary label for Classes 1, 2, 3, 4, 5, 6, and 8. However, the label must meet the other specifications in the HMR.
Special labels (172.403, 172.407, 172.450)
Specific definitions for terms associated with markings, placards, and labels clarify their meaning.
Definitions for markings terminology
Bulk packagings: Other than vessels or barges, and including transport vehicles or freight containers, are bulk packagings in which hazardous materials are loaded with no intermediate form of containment and that have:
A large packaging in which hazardous materials are loaded with an intermediate form of containment, such as one or more articles or inner packagings, is also a bulk packaging.
Cargo aircraft only: This aircraft is used to transport cargo and is not engaged in carrying passengers. The terms “cargo aircraft only,” “cargo-only aircraft,” and “cargo aircraft” have the same meaning.
Limited quantity: When specified as such in a section applicable to a particular material, it means the maximum amount of a hazardous material for which there is a specific labeling or packaging exception.
Marking: This consists of a descriptive name, identification number, instructions, cautions, weight, specifications, or United Nations (UN) marks, or combinations thereof, required by the Hazardous Materials Regulations (HMR) on outer packagings of hazardous materials.
Non-bulk packagings: These packagings have:
Technical name: This is a recognized chemical name or microbiological name currently used in scientific and technical handbooks, journals, and texts. Generic descriptions are authorized for use as technical names provided they readily identify the general chemical group or microbiological group. Examples of acceptable generic chemical descriptions are organic phosphate compounds, petroleum aliphatic hydrocarbons, and tertiary amines. For proficiency testing only, generic microbiological descriptions such as bacteria, mycobacteria, fungus, and viral samples may be used. Except for names that appear in Subpart B of Part 172 of this subchapter, trade names may not be used as technical names.
Definitions associated with placards
Freight container: A reusable container having a volume of 64 cubic feet or more, designed and constructed to permit being lifted with its contents intact and intended primarily for containment of packages (in unit form) during transportation.
Rail car: A car designed to carry freight or non-passenger personnel by rail, and includes a box car, flat car, gondola car, hopper car, tank car, and occupied caboose.
Residue: The hazardous material remaining in a packaging, including a tank car, after its contents have been unloaded to the maximum extent practicable and before the packaging is either refilled or cleaned of hazardous material and purged to remove any hazardous vapors.
Subsidiary hazard: The hazard of a material other than the primary hazard.
Transport vehicle: A cargo-carrying vehicle such as an automobile, van, tractor, truck, semitrailer, tank car, or rail car used for transportation of cargo by any mode. Each cargo-carrying body (trailer, rail car, etc.) is a separate transport vehicle.
Unit load device: Any type of freight container, aircraft container, aircraft pallet with a net, or aircraft pallet with a net over an igloo.
Definitions of terms associated with labels
Dewar flask: An insulating storage vessel that greatly lengthens the time during which its contents remain hotter or cooler than the flask’s surroundings. The vacuum flask consists of two flasks, placed one within the other and joined at the neck. The gap between the two flasks is partially evacuated of air, creating a near-vacuum that significantly reduces heat transfer by conduction or convection.
Limited quantity: When specified as such in a section applicable to a particular material, it means the maximum amount of a hazardous material for which there is a specific labeling or packaging exception.
Overpack: An enclosure used by a single consignor to provide protection or convenience in handling a package or to consolidate two or more packages. Overpack does not include a transport vehicle, freight container, or aircraft unit load device.
Examples of overpacks are one or more packages:
Primary label: A hazard warning label that corresponds with the primary hazard of the material.
Subsidiary label: A hazard warning label that corresponds with the subsidiary hazard of the material.
Markings provide important information about the contents of a packaging, freight container, or transport vehicle and help warn of hazards posed by that material during transport. Markings give additional information, not provided by labels or placards, about the hazardous material in a package or vehicle.
Who is responsible for markings?
Marking requirements apply to non-bulk and bulk packagings transported by rail, air, vessel, and highway. Certain requirements specifically apply to transport vehicles and freight containers.
The individual who prepares non-bulk packages of hazardous material for transport is responsible for marking the package. This responsibility includes:
In most cases, the responsibility for marking bulk packagings, freight containers, and transport vehicles rests with the individual initiating the shipment. The carrier is responsible for replacing identification number markings that are lost, damaged, or destroyed during transit.
Types of markings that are prohibited
No packaging may be marked with a proper shipping name or identification number unless the packaging contains the identified material or its residue.
Specifications for markings
To withstand conditions normally encountered during transportation, all markings must be:
Manufacturer/specification packaging marking (178.503)
Most authorized packagings for hazardous materials must be marked with a United Nations (UN) packaging marking (for non-bulk packaging) or a specification packaging marking (such as DOT 406). For more information on these markings, refer to the Markings section under packaging definitions.
Most non-bulk packagings must be marked with the following information:
Description/proper shipping name (172.308)
The description/proper shipping name as shown in Column (2) of the Hazardous Materials Table must be marked on the non-bulk package.
Abbreviations are usually not allowed in a proper shipping name marking. The only exception includes abbreviations appearing as part of the authorized description in Column (2) of the Hazardous Materials Table, such as “TNT” or “PCB”.
Technical names (172.301)
Any package that contains hazardous materials described by a proper shipping name preceded by the symbol “G” in Column (1) of the Hazardous Materials Table must be marked with the technical name in parentheses in association with the proper shipping name. However, a technical name should not be marked on the outer package of a Division 6.2 material.
Identification number (172.301)
The identification number shown in Column (3) of the Hazardous Materials Table, for the description/proper shipping name being used, must be marked on the package. The appropriate “UN” “NA,” or “ID” prefix must be included.
Identification numbers marked on non-bulk packagings must meet specific size requirements. The identification numbers must be at least 0.47 inches (12 mm) high. On smaller packages — 8 gallons (30 L) or less, 66 pounds (30 kg) maximum, or cylinders with a water capacity of 16 gallons (60 L) or less — the identification numbers must be at least 0.24 inches (6 mm) high. For even smaller packages, capacity of 1.32 gallons (5 L) or 11 pounds (5 kg) or less, the size of the identification numbers must be appropriate for the package size.
Name and address (172.301)
The name and address of the consignee (receiver/buyer) or consignor (shipper/seller) must be marked on the package unless:
Special permit packagings (172.302)
The special permit number is required to be plainly and durably marked on the packaging if it is authorized for use under a special permit. The package should be marked “DOT-SP (followed by the special permit number).”
Hazardous substances (172.324)
Non-bulk packagings that contain a reportable quantity (RQ) of a hazardous substance must be marked with the letters “RQ” in association with the proper shipping name.
PCBs (761.40, 761.45)
Polychlorinated biphenyls (PCBs) are hazard substances that must be transported in compliance with the Hazardous Materials Regulations (HMR) and special additional requirements of the U.S. Environmental Protection Agency (EPA).
The HMR require the proper shipping name, identification number, and RQ to be marked on each non-bulk package.
EPA regulations require the package to be marked with the PCB mark and a minimum size 6 x 6 inches (152.4 mm x 152.4 mm). This PCB mark may be reduced proportionately to a minimum of 2 x 2 inches (50.8 mm x 50.8 mm) to fit on PCB articles or equipment.
An even smaller rectangular PCB mark may be used on small packages. This small rectangular PCB mark may be proportionately reduced to a minimum of 0.4 x 0.8 inches (10.16 mm x 20.32 mm) to fit on PCB articles or equipment.
EPA regulations also require a vehicle to be marked on each side and each end with this marking, if transporting PCB containers that contain more than 99.4 pounds (45 kg) of liquid PCBs in concentrations of 50 to 500 ppm.
Large quantities of non-bulk packages
A transport vehicle or freight container loaded with only a single hazardous material in non-bulk packages must be marked, on each side and each end with the identification number specified for the material, subject to the following:
The above requirement does not apply to Class 1 materials, Class 7 materials, or non-bulk packagings for which identification numbers are not required, such as limited quantity materials.
Large quantities of non-bulk inhalation hazards
A transport vehicle or freight container loaded at one loading facility with 2,205 pounds (1,000 kg) or more of non-bulk packages containing a material poisonous by inhalation (in Hazard Zone A or B), having the same shipping name and identification number, must be marked with the identification number specified for the material, on each side and each end.
If the transport vehicle or freight container contains more than one inhalation hazard material that meets the above identification number marking requirement, it must be marked with the identification number for only one material. That one identification number is determined by the following:
Unless specifically excepted, all bulk packagings of hazardous materials must be marked with the identification number(s) of the contents. These numbers, unless otherwise provided, must be marked:
Identification number display
There are three ways in which identification numbers may be displayed:
If the identification number markings on a portable tank or cargo tank are not visible, the transport vehicle or freight container used to transport the tank must also be marked with the numbers, on each side and each end.
When a tank is permanently installed within an enclosed cargo body of a transport vehicle or freight container, the identification number marking need only be displayed on the sides and ends of the tank that are visible when the enclosed cargo body is opened or entered.
Identification numbers are not required on the ends of portable tanks and cargo tanks having more than one compartment if hazardous materials having different identification numbers are transported in the compartments. The identification numbers on the sides of the tank must be displayed in the same sequence as the compartments containing the materials they identify.
Special permit packaging
When a bulk packaging is labeled instead of placarded, the identification number markings may be displayed on the bulk packaging in the same manner as would be required for a non-bulk packaging.
DOT-SP (followed by the special permit number) is required to be marked on the packaging if it is authorized for use under a special permit.
Portable tanks
In addition to displaying the applicable identification number, portable tanks must be marked with:
IBCs
When an intermediate bulk container (IBC) is labeled instead of placarded, the IBC may display the proper shipping name and identification number markings as required by 172.301(a)(1) for non-bulk packagings. These smaller markings may be used in place of the identification number marking on an orange panel, placard, or white square-on-point configuration.
Cargo tanks
In addition to the identification number, cargo tanks (except for certain nurse tanks) that are used to transport gases (Class 2 material) must be marked on each side and each end with the proper shipping name or appropriate common name of the gas.
Each specification cargo tank that successfully completes a test/inspection must be marked with the date (month and year) and the type of test/inspection completed. This marking must be displayed near the specification plate or anywhere on the front head. The type of test/inspection may be abbreviated as follows:
Tank cars
In addition to the identification number, tank cars — when required by a special provision to the Hazardous Materials Table or by 172.330 — must be marked on each side with the proper shipping name or appropriate common name.
In addition to the identification number marking, multi-unit tank car tanks must be marked on two opposing sides with the proper shipping name or appropriate common name.
If the proper shipping name for a hazardous material in a bulk packaging has been changed, the bulk packaging may not need to be remarked if:
A bulk packaging used to transport petroleum crude oil containing hydrogen sulfide (sour crude oil) in sufficient concentrations that the vapors may present an inhalation hazard must be marked with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) toxic pictogram or a warning statement such as “Danger: Possible Hydrogen Sulfide Inhalation Hazard.” The marking must be displayed at each location (manhole, loading head) where exposure to hydrogen sulfide vapors may occur.
A package containing a limited quantity of hazardous materials is required to be marked with one of the following:
The width of the border forming the square-on-point marking must be at least 0.08 inches (2 mm). Each side of the marking must be at least 3.94 inches (100 mm). If the package size requires a reduced size marking, then each side of the marking may be reduced to no less than 1.97 inches (50 mm). For cargo transport units transported by water, each side of the marking must have a minimum size of 9.84 inches (250 mm).
Additional markings may be required depending on the hazardous material being transported or the type of package used.
Hazardous wastes
Proper shipping names marked on non-bulk packages of hazardous waste are not required to include the word “waste” if the U.S. Environmental Protection Agency (EPA) marking is displayed in accordance with 40 CFR Section 262.32.
Orientation arrow markings
Combination packagings that have inner packagings containing liquid hazardous materials, single packaging fitted with vents, or open cryogenic receptacles must be marked with orientation arrows. These arrows must be displayed on two opposite vertical sides of the packaging — with the arrows pointing in the correct upward direction.
Orientation arrows are not required on packages that contain:
Inhalation hazards
Packagings that contain materials poisonous-by-inhalation must be marked “INHALATION HAZARD” in association with required labels or placards or the proper shipping name. The “INHALATION HAZARD” marking is not required if the package bears a poison gas or poison inhalation hazard label (or placard) displaying the words “INHALATION HAZARD.”
This marking on bulk packages must be on two opposite sides and have:
Poisons
Non-bulk plastic outer packagings used as single or composite packagings for Division 6.1 materials must be permanently marked with the word “POISON” — either by embossing or other durable means. This marking must be at least 0.25 inches (6.3 mm) in height and located within 6 inches (150 mm) of the closure of the packaging.
A package containing a Division 6.1 (poison) material in Packing Group III may be marked “PG III” adjacent to the “POISON” label.
Keep away from heat (172.(317)
For transportation by aircraft, packages containing self-reactive substances of Division 4.1 or organic peroxides of Division 5.2 must be marked with the “KEEP AWAY FROM HEAT” handling mark. This marking must be at least 4.1 inches (105 mm) in height and 2.9 inches (74 mm) in width.
Explosive materials (172.320)
A package of Class 1 material must be marked with the EX-number for each substance, article, or device contained therein unless it is excepted from this marking as specified in 172.320. In some situations, no marking is required; for others, a national stock number or product code may be used.
When more than five different Class 1 materials are packed in the same package, no more than five of the numbers, codes, or a combination thereof are required to be marked on the package.
Marine pollutants
Non-bulk packagings that contain marine pollutants and are offered for transportation by vessel must be marked with:
The marine pollutant marking is not required on single packagings or combination packagings where each single package or each inner packaging of combination packagings has:
The marine pollutant marking is not required on a combination packaging containing a marine pollutant (other than a severe marine pollutant) in inner packagings, each of which contains:
Non-bulk packagings of marine pollutants transported by motor vehicle, rail car, or aircraft are not subject to marine pollutant requirements.
Bulk packagings with a capacity of 1,000 gallons (3,785 L) or more and that contain marine pollutants must be marked on each side and each end with the marine pollutant marking. A bulk packaging with a capacity of less than 1,000 gallons (3,785 L) must be marked on two opposing sides or ends with the marine pollutant marking.
Did you know?
Except for transportation by vessel, a bulk packaging, freight container, or transport vehicle that bears a label or placard is not required to display the marine pollutant marking.
A package of limited quantity material that is marked with a square-on-point limited quantity marking is not required to display the marine pollutant marking.
The symbol and border must be black on a white background, or be of a contrasting color to the surface on which the marking is displayed. The width of the border must be at least 0.08 inches (2 mm). Each side of the marking must be at least 3.9 inches (100 mm) for non-bulk packages and bulk packages with a capacity of less than 1,000 gallons (3,785 L). For all other bulk packages, each side of the marking must be at least 9.8 inches (250 mm).
Elevated-temperature materials
Most bulk packages that contain an elevated-temperature material must be marked on two opposing sides with the word “HOT” — in black or white Gothic lettering on a contrasting background. This marking must be displayed on the packaging itself or in black lettering on a white square-on-point configuration that is the same size as a placard.
Bulk packages that contain molten aluminum or molten sulfur must be marked “MOLTEN ALUMINUM” or “MOLTEN SULFUR” as appropriate, instead of with the word “HOT.
For bulk packages that must be marked “HOT,” “MOLTEN ALUMINUM,” or “MOLTEN SULFUR,” the letters must be at least:
The Hazardous Materials Regulations (HMR) allow the “HOT” marking and identification number marking to be combined on the same white square-on-point configuration. In this case, the identification number must be displayed in the center of the white square-on-point configuration, and the word “HOT” must be displayed in the upper corner. The word “HOT” must be in black letters having a height of at least 2 inches (50 mm).
Radioactive materials (172.310)
Each package containing Class 7 (radioactive) materials must also be marked with:
Regulated medical waste (172.323)
A bulk packaging containing a regulated medical waste must be marked with the “BIOHAZARD” marking, visible from the direction it faces:
The “BIOHAZARD” marking must be at least 6 inches (152.4 mm) on each side. This marking may be displayed on a white square-on-point configuration.
Non-odorized LPG (172.301, 172.326, 172.328, 172.330)
No person may offer or transport certain specification cylinders, a portable tank, cargo tank, or tank car containing liquefied petroleum gas (LPG) that is not odorized unless the words “NON-ODORIZED” or “NOT ODORIZED” appear near the proper shipping name. This marking must appear on two opposing sides on portable tanks, cargo tanks, and tank cars.
Overpacks
Each overpack:
Fumigant marking
Each truck body or trailer, rail car, or freight container containing lading that has been fumigated or treated with any material, or is undergoing fumigation, must have a “FUMIGANT” marking displayed so it can be seen by any person attempting to enter the vehicle or container.
The printing on the “FUMIGANT” marking must be black on a white background. The size of the white background must be at least 15.75 inches (400 mm) wide and at least 11.8 inches (300 mm) high. The width of the border must be at least 0.08 inches (2 mm). Text on this marking must be at least 0.98 inches (25 mm). The technical name of the fumigant must be entered in the appropriate place (*) on the marking.
The “FUMIGANT” marking must be displayed until the truck body or trailer, rail car, or freight container has been completely ventilated.
Reverse logistics
Reverse logistics is the offering or transporting of goods by motor vehicle from a retail store for return to the manufacturer, supplier, or distribution facility for the purpose of capturing value (credit), recall, replacement, recycling, or similar reason. This does not include hazardous waste.
Materials involved in reverse logistics are excepted from many of the Hazardous Materials Regulations (HMR). However, shipments of reverse logistics materials must be marked with the limited quantity marking or the words “REVERSE LOGISTICS – HIGHWAY TRANSPORT ONLY – UNDER 49 CFR 173.157.”
Small quantities (173.4)
When transported by highway or rail only, packages containing small quantities of materials meeting the requirements in Section 173.4 must be marked with the statement “This package conforms to 49 CFR 173.4 for domestic highway or rail transport only.”
Excepted quantities (173.4a)
When transported by air or vessel only, packages containing excepted quantities of materials meeting the requirements in Section 173.4a must be marked with the excepted quantities marking. The “*” must be replaced with the hazard class or division of each hazardous material in the package. The “**” must be replaced with the name of the shipper or consignee, if not shown elsewhere on the package. The hatching must be the same color, black or red on a contrasting background. The marking must be 3.9 inches (100 mm) by 3.9 inches (100 mm).
Most non-bulk packagings must be marked with the following information:
Description/proper shipping name (172.308)
The description/proper shipping name as shown in Column (2) of the Hazardous Materials Table must be marked on the non-bulk package.
Abbreviations are usually not allowed in a proper shipping name marking. The only exception includes abbreviations appearing as part of the authorized description in Column (2) of the Hazardous Materials Table, such as “TNT” or “PCB”.
Technical names (172.301)
Any package that contains hazardous materials described by a proper shipping name preceded by the symbol “G” in Column (1) of the Hazardous Materials Table must be marked with the technical name in parentheses in association with the proper shipping name. However, a technical name should not be marked on the outer package of a Division 6.2 material.
Identification number (172.301)
The identification number shown in Column (3) of the Hazardous Materials Table, for the description/proper shipping name being used, must be marked on the package. The appropriate “UN” “NA,” or “ID” prefix must be included.
Identification numbers marked on non-bulk packagings must meet specific size requirements. The identification numbers must be at least 0.47 inches (12 mm) high. On smaller packages — 8 gallons (30 L) or less, 66 pounds (30 kg) maximum, or cylinders with a water capacity of 16 gallons (60 L) or less — the identification numbers must be at least 0.24 inches (6 mm) high. For even smaller packages, capacity of 1.32 gallons (5 L) or 11 pounds (5 kg) or less, the size of the identification numbers must be appropriate for the package size.
Name and address (172.301)
The name and address of the consignee (receiver/buyer) or consignor (shipper/seller) must be marked on the package unless:
Special permit packagings (172.302)
The special permit number is required to be plainly and durably marked on the packaging if it is authorized for use under a special permit. The package should be marked “DOT-SP (followed by the special permit number).”
Hazardous substances (172.324)
Non-bulk packagings that contain a reportable quantity (RQ) of a hazardous substance must be marked with the letters “RQ” in association with the proper shipping name.
PCBs (761.40, 761.45)
Polychlorinated biphenyls (PCBs) are hazard substances that must be transported in compliance with the Hazardous Materials Regulations (HMR) and special additional requirements of the U.S. Environmental Protection Agency (EPA).
The HMR require the proper shipping name, identification number, and RQ to be marked on each non-bulk package.
EPA regulations require the package to be marked with the PCB mark and a minimum size 6 x 6 inches (152.4 mm x 152.4 mm). This PCB mark may be reduced proportionately to a minimum of 2 x 2 inches (50.8 mm x 50.8 mm) to fit on PCB articles or equipment.
An even smaller rectangular PCB mark may be used on small packages. This small rectangular PCB mark may be proportionately reduced to a minimum of 0.4 x 0.8 inches (10.16 mm x 20.32 mm) to fit on PCB articles or equipment.
EPA regulations also require a vehicle to be marked on each side and each end with this marking, if transporting PCB containers that contain more than 99.4 pounds (45 kg) of liquid PCBs in concentrations of 50 to 500 ppm.
Large quantities of non-bulk packages
A transport vehicle or freight container loaded with only a single hazardous material in non-bulk packages must be marked, on each side and each end with the identification number specified for the material, subject to the following:
The above requirement does not apply to Class 1 materials, Class 7 materials, or non-bulk packagings for which identification numbers are not required, such as limited quantity materials.
Large quantities of non-bulk inhalation hazards
A transport vehicle or freight container loaded at one loading facility with 2,205 pounds (1,000 kg) or more of non-bulk packages containing a material poisonous by inhalation (in Hazard Zone A or B), having the same shipping name and identification number, must be marked with the identification number specified for the material, on each side and each end.
If the transport vehicle or freight container contains more than one inhalation hazard material that meets the above identification number marking requirement, it must be marked with the identification number for only one material. That one identification number is determined by the following:
Large quantities of non-bulk packages
A transport vehicle or freight container loaded with only a single hazardous material in non-bulk packages must be marked, on each side and each end with the identification number specified for the material, subject to the following:
The above requirement does not apply to Class 1 materials, Class 7 materials, or non-bulk packagings for which identification numbers are not required, such as limited quantity materials.
Large quantities of non-bulk inhalation hazards
A transport vehicle or freight container loaded at one loading facility with 2,205 pounds (1,000 kg) or more of non-bulk packages containing a material poisonous by inhalation (in Hazard Zone A or B), having the same shipping name and identification number, must be marked with the identification number specified for the material, on each side and each end.
If the transport vehicle or freight container contains more than one inhalation hazard material that meets the above identification number marking requirement, it must be marked with the identification number for only one material. That one identification number is determined by the following:
Unless specifically excepted, all bulk packagings of hazardous materials must be marked with the identification number(s) of the contents. These numbers, unless otherwise provided, must be marked:
Identification number display
There are three ways in which identification numbers may be displayed:
If the identification number markings on a portable tank or cargo tank are not visible, the transport vehicle or freight container used to transport the tank must also be marked with the numbers, on each side and each end.
When a tank is permanently installed within an enclosed cargo body of a transport vehicle or freight container, the identification number marking need only be displayed on the sides and ends of the tank that are visible when the enclosed cargo body is opened or entered.
Identification numbers are not required on the ends of portable tanks and cargo tanks having more than one compartment if hazardous materials having different identification numbers are transported in the compartments. The identification numbers on the sides of the tank must be displayed in the same sequence as the compartments containing the materials they identify.
Special permit packaging
When a bulk packaging is labeled instead of placarded, the identification number markings may be displayed on the bulk packaging in the same manner as would be required for a non-bulk packaging.
DOT-SP (followed by the special permit number) is required to be marked on the packaging if it is authorized for use under a special permit.
Portable tanks
In addition to displaying the applicable identification number, portable tanks must be marked with:
IBCs
When an intermediate bulk container (IBC) is labeled instead of placarded, the IBC may display the proper shipping name and identification number markings as required by 172.301(a)(1) for non-bulk packagings. These smaller markings may be used in place of the identification number marking on an orange panel, placard, or white square-on-point configuration.
Cargo tanks
In addition to the identification number, cargo tanks (except for certain nurse tanks) that are used to transport gases (Class 2 material) must be marked on each side and each end with the proper shipping name or appropriate common name of the gas.
Each specification cargo tank that successfully completes a test/inspection must be marked with the date (month and year) and the type of test/inspection completed. This marking must be displayed near the specification plate or anywhere on the front head. The type of test/inspection may be abbreviated as follows:
Tank cars
In addition to the identification number, tank cars — when required by a special provision to the Hazardous Materials Table or by 172.330 — must be marked on each side with the proper shipping name or appropriate common name.
In addition to the identification number marking, multi-unit tank car tanks must be marked on two opposing sides with the proper shipping name or appropriate common name.
If the proper shipping name for a hazardous material in a bulk packaging has been changed, the bulk packaging may not need to be remarked if:
A bulk packaging used to transport petroleum crude oil containing hydrogen sulfide (sour crude oil) in sufficient concentrations that the vapors may present an inhalation hazard must be marked with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) toxic pictogram or a warning statement such as “Danger: Possible Hydrogen Sulfide Inhalation Hazard.” The marking must be displayed at each location (manhole, loading head) where exposure to hydrogen sulfide vapors may occur.
Portable tanks
In addition to displaying the applicable identification number, portable tanks must be marked with:
IBCs
When an intermediate bulk container (IBC) is labeled instead of placarded, the IBC may display the proper shipping name and identification number markings as required by 172.301(a)(1) for non-bulk packagings. These smaller markings may be used in place of the identification number marking on an orange panel, placard, or white square-on-point configuration.
Cargo tanks
In addition to the identification number, cargo tanks (except for certain nurse tanks) that are used to transport gases (Class 2 material) must be marked on each side and each end with the proper shipping name or appropriate common name of the gas.
Each specification cargo tank that successfully completes a test/inspection must be marked with the date (month and year) and the type of test/inspection completed. This marking must be displayed near the specification plate or anywhere on the front head. The type of test/inspection may be abbreviated as follows:
Tank cars
In addition to the identification number, tank cars — when required by a special provision to the Hazardous Materials Table or by 172.330 — must be marked on each side with the proper shipping name or appropriate common name.
In addition to the identification number marking, multi-unit tank car tanks must be marked on two opposing sides with the proper shipping name or appropriate common name.
If the proper shipping name for a hazardous material in a bulk packaging has been changed, the bulk packaging may not need to be remarked if:
A bulk packaging used to transport petroleum crude oil containing hydrogen sulfide (sour crude oil) in sufficient concentrations that the vapors may present an inhalation hazard must be marked with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) toxic pictogram or a warning statement such as “Danger: Possible Hydrogen Sulfide Inhalation Hazard.” The marking must be displayed at each location (manhole, loading head) where exposure to hydrogen sulfide vapors may occur.
A package containing a limited quantity of hazardous materials is required to be marked with one of the following:
The width of the border forming the square-on-point marking must be at least 0.08 inches (2 mm). Each side of the marking must be at least 3.94 inches (100 mm). If the package size requires a reduced size marking, then each side of the marking may be reduced to no less than 1.97 inches (50 mm). For cargo transport units transported by water, each side of the marking must have a minimum size of 9.84 inches (250 mm).
Additional markings may be required depending on the hazardous material being transported or the type of package used.
Hazardous wastes
Proper shipping names marked on non-bulk packages of hazardous waste are not required to include the word “waste” if the U.S. Environmental Protection Agency (EPA) marking is displayed in accordance with 40 CFR Section 262.32.
Orientation arrow markings
Combination packagings that have inner packagings containing liquid hazardous materials, single packaging fitted with vents, or open cryogenic receptacles must be marked with orientation arrows. These arrows must be displayed on two opposite vertical sides of the packaging — with the arrows pointing in the correct upward direction.
Orientation arrows are not required on packages that contain:
Inhalation hazards
Packagings that contain materials poisonous-by-inhalation must be marked “INHALATION HAZARD” in association with required labels or placards or the proper shipping name. The “INHALATION HAZARD” marking is not required if the package bears a poison gas or poison inhalation hazard label (or placard) displaying the words “INHALATION HAZARD.”
This marking on bulk packages must be on two opposite sides and have:
Poisons
Non-bulk plastic outer packagings used as single or composite packagings for Division 6.1 materials must be permanently marked with the word “POISON” — either by embossing or other durable means. This marking must be at least 0.25 inches (6.3 mm) in height and located within 6 inches (150 mm) of the closure of the packaging.
A package containing a Division 6.1 (poison) material in Packing Group III may be marked “PG III” adjacent to the “POISON” label.
Keep away from heat (172.(317)
For transportation by aircraft, packages containing self-reactive substances of Division 4.1 or organic peroxides of Division 5.2 must be marked with the “KEEP AWAY FROM HEAT” handling mark. This marking must be at least 4.1 inches (105 mm) in height and 2.9 inches (74 mm) in width.
Explosive materials (172.320)
A package of Class 1 material must be marked with the EX-number for each substance, article, or device contained therein unless it is excepted from this marking as specified in 172.320. In some situations, no marking is required; for others, a national stock number or product code may be used.
When more than five different Class 1 materials are packed in the same package, no more than five of the numbers, codes, or a combination thereof are required to be marked on the package.
Marine pollutants
Non-bulk packagings that contain marine pollutants and are offered for transportation by vessel must be marked with:
The marine pollutant marking is not required on single packagings or combination packagings where each single package or each inner packaging of combination packagings has:
The marine pollutant marking is not required on a combination packaging containing a marine pollutant (other than a severe marine pollutant) in inner packagings, each of which contains:
Non-bulk packagings of marine pollutants transported by motor vehicle, rail car, or aircraft are not subject to marine pollutant requirements.
Bulk packagings with a capacity of 1,000 gallons (3,785 L) or more and that contain marine pollutants must be marked on each side and each end with the marine pollutant marking. A bulk packaging with a capacity of less than 1,000 gallons (3,785 L) must be marked on two opposing sides or ends with the marine pollutant marking.
Did you know?
Except for transportation by vessel, a bulk packaging, freight container, or transport vehicle that bears a label or placard is not required to display the marine pollutant marking.
A package of limited quantity material that is marked with a square-on-point limited quantity marking is not required to display the marine pollutant marking.
The symbol and border must be black on a white background, or be of a contrasting color to the surface on which the marking is displayed. The width of the border must be at least 0.08 inches (2 mm). Each side of the marking must be at least 3.9 inches (100 mm) for non-bulk packages and bulk packages with a capacity of less than 1,000 gallons (3,785 L). For all other bulk packages, each side of the marking must be at least 9.8 inches (250 mm).
Elevated-temperature materials
Most bulk packages that contain an elevated-temperature material must be marked on two opposing sides with the word “HOT” — in black or white Gothic lettering on a contrasting background. This marking must be displayed on the packaging itself or in black lettering on a white square-on-point configuration that is the same size as a placard.
Bulk packages that contain molten aluminum or molten sulfur must be marked “MOLTEN ALUMINUM” or “MOLTEN SULFUR” as appropriate, instead of with the word “HOT.
For bulk packages that must be marked “HOT,” “MOLTEN ALUMINUM,” or “MOLTEN SULFUR,” the letters must be at least:
The Hazardous Materials Regulations (HMR) allow the “HOT” marking and identification number marking to be combined on the same white square-on-point configuration. In this case, the identification number must be displayed in the center of the white square-on-point configuration, and the word “HOT” must be displayed in the upper corner. The word “HOT” must be in black letters having a height of at least 2 inches (50 mm).
Radioactive materials (172.310)
Each package containing Class 7 (radioactive) materials must also be marked with:
Regulated medical waste (172.323)
A bulk packaging containing a regulated medical waste must be marked with the “BIOHAZARD” marking, visible from the direction it faces:
The “BIOHAZARD” marking must be at least 6 inches (152.4 mm) on each side. This marking may be displayed on a white square-on-point configuration.
Non-odorized LPG (172.301, 172.326, 172.328, 172.330)
No person may offer or transport certain specification cylinders, a portable tank, cargo tank, or tank car containing liquefied petroleum gas (LPG) that is not odorized unless the words “NON-ODORIZED” or “NOT ODORIZED” appear near the proper shipping name. This marking must appear on two opposing sides on portable tanks, cargo tanks, and tank cars.
Overpacks
Each overpack:
Fumigant marking
Each truck body or trailer, rail car, or freight container containing lading that has been fumigated or treated with any material, or is undergoing fumigation, must have a “FUMIGANT” marking displayed so it can be seen by any person attempting to enter the vehicle or container.
The printing on the “FUMIGANT” marking must be black on a white background. The size of the white background must be at least 15.75 inches (400 mm) wide and at least 11.8 inches (300 mm) high. The width of the border must be at least 0.08 inches (2 mm). Text on this marking must be at least 0.98 inches (25 mm). The technical name of the fumigant must be entered in the appropriate place (*) on the marking.
The “FUMIGANT” marking must be displayed until the truck body or trailer, rail car, or freight container has been completely ventilated.
Reverse logistics
Reverse logistics is the offering or transporting of goods by motor vehicle from a retail store for return to the manufacturer, supplier, or distribution facility for the purpose of capturing value (credit), recall, replacement, recycling, or similar reason. This does not include hazardous waste.
Materials involved in reverse logistics are excepted from many of the Hazardous Materials Regulations (HMR). However, shipments of reverse logistics materials must be marked with the limited quantity marking or the words “REVERSE LOGISTICS – HIGHWAY TRANSPORT ONLY – UNDER 49 CFR 173.157.”
Small quantities (173.4)
When transported by highway or rail only, packages containing small quantities of materials meeting the requirements in Section 173.4 must be marked with the statement “This package conforms to 49 CFR 173.4 for domestic highway or rail transport only.”
Excepted quantities (173.4a)
When transported by air or vessel only, packages containing excepted quantities of materials meeting the requirements in Section 173.4a must be marked with the excepted quantities marking. The “*” must be replaced with the hazard class or division of each hazardous material in the package. The “**” must be replaced with the name of the shipper or consignee, if not shown elsewhere on the package. The hatching must be the same color, black or red on a contrasting background. The marking must be 3.9 inches (100 mm) by 3.9 inches (100 mm).
Hazardous materials placards correspond closely with the shape, color, and design of hazardous materials labels. However, placards are much larger than labels. Placards alert persons to potential dangers associated with the particular hazardous material contained in a motor vehicle, rail car, freight container, cargo tank, or portable tank.
Anyone offering or accepting hazardous materials for shipment in an amount that requires placards must ensure the material is placarded according to applicable sections of the Hazardous Materials Regulations (HMR).
Placarding requirements apply to each person who offers for transport or transports hazardous materials. The placarding requirements do not apply to the following materials:
Placards are used to identify the hazard or hazards of materials contained in bulk packagings, freight containers, unit load devices, transport vehicles, or rail cars.
Responsibility
The responsibility for affixing or supplying placards varies according to mode of transport and type of packaging used to transport the hazardous material.
For highway transport, the shipper is responsible for providing the appropriate placards to the driver. The driver is responsible for applying them correctly on the vehicle and maintaining them during transport. In addition, drivers are responsible for any placarding necessitated by aggregate shipments.
Bulk packagings (172.514)
The person who offers a bulk packaging containing a hazardous material for transportation is required to affix the required placards before or at the time the packaging is offered for transportation.
Freight containers and aircraft unit load devices (172.512)
Each person who offers for transportation and each person who loads and transports a hazardous material in a freight container or aircraft unit load device is required to affix the appropriate placards.
Transport vehicles (172.506, 177.823)
When a hazardous material is offered for transport by highway, the individual offering the material must provide the carrier with the required placards — before or at the same time the material is offered for transport — unless the appropriate placards are already affixed to the vehicle.
Typically, the carrier is forbidden from moving the vehicle until placards have been affixed. However, the carrier may move the vehicle before placarding in an emergency situation or when one of the following three conditions are met:
Rail cars (172.508)
When a hazardous material is offered for transport by rail, the individual offering the material must affix the required placard(s) to the rail car — unless the car is already properly placarded. The rail carrier may not accept a rail car for transport unless required placards are affixed.
Prohibited placarding (172.502)
No person may affix a placard to a packaging, freight container, unit load device, motor vehicle, or rail car unless the material being offered for transportation is a hazardous material, the placard applied represents the hazard of the material being offered, and placards conform to requirements in the Hazardous Materials Regulations (HMR).
Signs, advertisements, slogans (such as “Drive Safely”), or other devices that could be confused with a prescribed placard are prohibited.
Permissive placarding (172.502)
Placards may be displayed for a hazardous material, even when not required, if the hazardous material is present and the placarding conforms to regulations.
A bulk packaging, freight container, unit load device, transport vehicle, or rail car placarded according to Canada’s Transport Dangerous Goods (TDG) Regulations, the International Maritime Dangerous Goods (IMDG) Code, or the United Nations (UN) Recommendations is allowed.
Placarding tables (172.504)
Placarding requirements vary according to the category of material (hazard class, division, packing group, or description) being transported and type of packaging (bulk or non-bulk) containing the material. Each bulk packaging, freight container, unit load device, transport vehicle, or rail car containing hazardous material must be placarded on each side and each end (with some exceptions) with the type of placards specified in Table 1 or Table 2 of Section 172.504.
To determine what placards are required, one must know:
The most dangerous categories of hazardous materials are shown in Table 1 of 172.504. Any quantity of material falling within the categories listed in Table 1 must be placarded.
The remaining hazard categories are assigned to Table 2. Any quantity of these materials also must be placarded, but the regulations provide some exceptions under certain conditions.
Less than 1,001 pounds of Table 2 materials
A transport vehicle or freight container that contains less than 1,001 pounds (454 kg) aggregate gross weight of hazardous materials in non-bulk packages covered by Table 2 is not required to display placards. This exception does not apply to bulk packages or materials with subsidiary hazards that must be placarded according to 172.505.
Did you know?
A Class 9 placard is not required for domestic transportation. However, a bulk packaging must be marked with the appropriate identification number as required by the Hazardous Materials Regulations (HMR).
If a transport vehicle, rail car, freight container, or unit load device contains non-bulk packagings of two or more categories of Table 2 materials, the “DANGEROUS” placard may be displayed instead of the separate placards specified in Table 2.
When 2,205 pounds (1,000 kg) or more of one hazard category is loaded at one facility on one vehicle, rail car, freight container, or unit load device, the “DANGEROUS” placard cannot be used for that one hazard category; instead, the placard specified in Table 2 must be displayed.
If three or more different categories of Table 2 materials are in one vehicle, rail car, freight container, or unit load device, and one material is over the 2,205-lb (1,000-kg) limit and requires an individual class placard, the “DANGEROUS” placard may still be used for the other categories of Table 2 material that fall below the 2,205-lb (1,000-kg) limit.
Placard exceptions by hazard class
Class 1 (172.504)
When more than one division placard is required for Class 1 materials on a transport vehicle, rail car, freight container, or unit load device, only the placard representing the lowest division number must be displayed.
The “EXPLOSIVES” 1.4 placard is not required for those Division 1.4 Compatibility Group S (1.4S) materials that are not required to be labeled 1.4S.
For shipments of Class 1 (explosive) materials by aircraft or vessel, the applicable compatibility group letter must be displayed on the required placards.
Gases (172.504)
A “NON-FLAMMABLE GAS” placard is not required on a motor vehicle containing a non-flammable gas if the vehicle contains flammable gas or oxygen and is placarded “FLAMMABLE GAS” or “OXYGEN,” as required.
The “OXYGEN” placard may be used for domestic shipments of oxygen, compressed or oxygen, refrigerated liquid in place of a “NON-FLAMMABLE GAS” placard.
Flammables (172.504)
A “COMBUSTIBLE” placard is not required on a cargo tank, portable tank, or compartmented tank car containing both flammable and combustible liquids when placarded “FLAMMABLE.”
Oxidizers (172.504)
“OXIDIZER” placards are not required for Division 5.1 materials on freight containers, unit load devices, transport vehicles, or rail cars that also contain Division 1.1 or 1.2 materials and are placarded with “EXPLOSIVES” 1.1 or 1.2 placards, as required.
For transportation by transport vehicle or rail car only: An “OXIDIZER” placard is not required for Division 5.1 materials on a transport vehicle, rail car, or freight container that also contains Division 1.5 materials and is placarded with “EXPLOSIVES” 1.5 placards, as required.
Poisons (172.504)
For domestic transportation:
For Division 6.1, Packing Group III materials, a “POISON” placard may be modified to display the text “PG III” below the midline of the placard in place of the word “POISON.”
Class 9 (172.504)
Class 9 placards are not required for domestic transportation.
Freight containers/unit load devices and placards for rail (172.512)
A motor vehicle transporting freight containers or aircraft unit load devices that are not required to be placarded is not required to display placards.
Freight containers and unit load devices being transported for delivery to a consignee immediately after an air or water shipment are also allowed to use the exception for less than 1,001 pounds (454 kg) of Table 2 materials.
A freight container or aircraft unit load device that is only transported by air and is prepared according to Part 7, Chapter 2, Section 2.8 of the International Civil Aviation Organization (ICAO) Technical Instructions is not required to be placarded.
Rail (172.504)
A rail car loaded with a transport vehicle or freight container that is not required to be placarded is not required to display placards.
Primary and subsidiary placards
There are two types of placards:
Generally, only primary placards are displayed. Section 172.505 of the Hazardous Materials Regulations (HMR) requires additional placards to be displayed under certain conditions for several subsidiary hazards. This includes “POISON GAS,” “POISON INHALATION HAZARD,” “POISON,” “CORROSIVE,” and “DANGEROUS WHEN WET.” Other subsidiary placards are permitted to be displayed but are not required.
Placard specifications
To be in compliance, all placards must meet the following specifications:
Tagboard placards must:
White square background
Transportation by highway (172.507)
A square background behind the placard is required when a motor vehicle is used to transport a highway route-controlled quantity of radioactive material.
Placard placement (172.516)
Each placard affixed to a motor vehicle or rail car must be readily visible from the direction it faces — except from the direction of another vehicle or rail car to which the vehicle or rail car is coupled.
The placard placement for the front of a vehicle may be on the front of the truck-tractor instead of, or in addition to, the placard on the front of the cargo-carrying body (e.g., trailer or semitrailer).
Best practice
Most carriers place the front placard on the front of the tractor to make it easier for the driver to change or remove the placard if necessary.
Placards displayed on freight containers or portable tanks loaded on (not enclosed in) a motor vehicle or rail car may be used to meet placarding requirements for the motor vehicle or rail car.
In addition, each placard on a transport vehicle, bulk packaging, unit load device, or freight container must be:
Bulk packagings (172.514)
In most situations, a bulk packaging containing hazardous materials that requires placards must be placarded on each side and each end. Each bulk packaging that previously contained a hazardous material requiring placards must remain placarded when emptied unless it:
The following bulk packagings may be placarded on only two opposite sides or may be labeled instead of placarded:
Flexible bulk containers may be placarded in two opposing positions.
Freight containers and aircraft unit load devices (172.512)
A freight container or aircraft unit load device with a capacity less than 640 cubic feet (18 m3) is required to display one placard as specified in Section 172.504. This requirement does not apply if the freight container or unit load device:
Freight containers with a capacity of less than 640 cubic feet that are not transported by air do not have to be placarded — they may be labeled instead.
Prohibited placarding (172.502)
No person may affix a placard to a packaging, freight container, unit load device, motor vehicle, or rail car unless the material being offered for transportation is a hazardous material, the placard applied represents the hazard of the material being offered, and placards conform to requirements in the Hazardous Materials Regulations (HMR).
Signs, advertisements, slogans (such as “Drive Safely”), or other devices that could be confused with a prescribed placard are prohibited.
Permissive placarding (172.502)
Placards may be displayed for a hazardous material, even when not required, if the hazardous material is present and the placarding conforms to regulations.
A bulk packaging, freight container, unit load device, transport vehicle, or rail car placarded according to Canada’s Transport Dangerous Goods (TDG) Regulations, the International Maritime Dangerous Goods (IMDG) Code, or the United Nations (UN) Recommendations is allowed.
Placarding tables (172.504)
Placarding requirements vary according to the category of material (hazard class, division, packing group, or description) being transported and type of packaging (bulk or non-bulk) containing the material. Each bulk packaging, freight container, unit load device, transport vehicle, or rail car containing hazardous material must be placarded on each side and each end (with some exceptions) with the type of placards specified in Table 1 or Table 2 of Section 172.504.
To determine what placards are required, one must know:
The most dangerous categories of hazardous materials are shown in Table 1 of 172.504. Any quantity of material falling within the categories listed in Table 1 must be placarded.
The remaining hazard categories are assigned to Table 2. Any quantity of these materials also must be placarded, but the regulations provide some exceptions under certain conditions.
Less than 1,001 pounds of Table 2 materials
A transport vehicle or freight container that contains less than 1,001 pounds (454 kg) aggregate gross weight of hazardous materials in non-bulk packages covered by Table 2 is not required to display placards. This exception does not apply to bulk packages or materials with subsidiary hazards that must be placarded according to 172.505.
Did you know?
A Class 9 placard is not required for domestic transportation. However, a bulk packaging must be marked with the appropriate identification number as required by the Hazardous Materials Regulations (HMR).
If a transport vehicle, rail car, freight container, or unit load device contains non-bulk packagings of two or more categories of Table 2 materials, the “DANGEROUS” placard may be displayed instead of the separate placards specified in Table 2.
When 2,205 pounds (1,000 kg) or more of one hazard category is loaded at one facility on one vehicle, rail car, freight container, or unit load device, the “DANGEROUS” placard cannot be used for that one hazard category; instead, the placard specified in Table 2 must be displayed.
If three or more different categories of Table 2 materials are in one vehicle, rail car, freight container, or unit load device, and one material is over the 2,205-lb (1,000-kg) limit and requires an individual class placard, the “DANGEROUS” placard may still be used for the other categories of Table 2 material that fall below the 2,205-lb (1,000-kg) limit.
Placard exceptions by hazard class
Class 1 (172.504)
When more than one division placard is required for Class 1 materials on a transport vehicle, rail car, freight container, or unit load device, only the placard representing the lowest division number must be displayed.
The “EXPLOSIVES” 1.4 placard is not required for those Division 1.4 Compatibility Group S (1.4S) materials that are not required to be labeled 1.4S.
For shipments of Class 1 (explosive) materials by aircraft or vessel, the applicable compatibility group letter must be displayed on the required placards.
Gases (172.504)
A “NON-FLAMMABLE GAS” placard is not required on a motor vehicle containing a non-flammable gas if the vehicle contains flammable gas or oxygen and is placarded “FLAMMABLE GAS” or “OXYGEN,” as required.
The “OXYGEN” placard may be used for domestic shipments of oxygen, compressed or oxygen, refrigerated liquid in place of a “NON-FLAMMABLE GAS” placard.
Flammables (172.504)
A “COMBUSTIBLE” placard is not required on a cargo tank, portable tank, or compartmented tank car containing both flammable and combustible liquids when placarded “FLAMMABLE.”
Oxidizers (172.504)
“OXIDIZER” placards are not required for Division 5.1 materials on freight containers, unit load devices, transport vehicles, or rail cars that also contain Division 1.1 or 1.2 materials and are placarded with “EXPLOSIVES” 1.1 or 1.2 placards, as required.
For transportation by transport vehicle or rail car only: An “OXIDIZER” placard is not required for Division 5.1 materials on a transport vehicle, rail car, or freight container that also contains Division 1.5 materials and is placarded with “EXPLOSIVES” 1.5 placards, as required.
Poisons (172.504)
For domestic transportation:
For Division 6.1, Packing Group III materials, a “POISON” placard may be modified to display the text “PG III” below the midline of the placard in place of the word “POISON.”
Class 9 (172.504)
Class 9 placards are not required for domestic transportation.
Freight containers/unit load devices and placards for rail (172.512)
A motor vehicle transporting freight containers or aircraft unit load devices that are not required to be placarded is not required to display placards.
Freight containers and unit load devices being transported for delivery to a consignee immediately after an air or water shipment are also allowed to use the exception for less than 1,001 pounds (454 kg) of Table 2 materials.
A freight container or aircraft unit load device that is only transported by air and is prepared according to Part 7, Chapter 2, Section 2.8 of the International Civil Aviation Organization (ICAO) Technical Instructions is not required to be placarded.
Rail (172.504)
A rail car loaded with a transport vehicle or freight container that is not required to be placarded is not required to display placards.
Primary and subsidiary placards
There are two types of placards:
Generally, only primary placards are displayed. Section 172.505 of the Hazardous Materials Regulations (HMR) requires additional placards to be displayed under certain conditions for several subsidiary hazards. This includes “POISON GAS,” “POISON INHALATION HAZARD,” “POISON,” “CORROSIVE,” and “DANGEROUS WHEN WET.” Other subsidiary placards are permitted to be displayed but are not required.
Placard specifications
To be in compliance, all placards must meet the following specifications:
Tagboard placards must:
White square background
Transportation by highway (172.507)
A square background behind the placard is required when a motor vehicle is used to transport a highway route-controlled quantity of radioactive material.
Placard placement (172.516)
Each placard affixed to a motor vehicle or rail car must be readily visible from the direction it faces — except from the direction of another vehicle or rail car to which the vehicle or rail car is coupled.
The placard placement for the front of a vehicle may be on the front of the truck-tractor instead of, or in addition to, the placard on the front of the cargo-carrying body (e.g., trailer or semitrailer).
Best practice
Most carriers place the front placard on the front of the tractor to make it easier for the driver to change or remove the placard if necessary.
Placards displayed on freight containers or portable tanks loaded on (not enclosed in) a motor vehicle or rail car may be used to meet placarding requirements for the motor vehicle or rail car.
In addition, each placard on a transport vehicle, bulk packaging, unit load device, or freight container must be:
Bulk packagings (172.514)
In most situations, a bulk packaging containing hazardous materials that requires placards must be placarded on each side and each end. Each bulk packaging that previously contained a hazardous material requiring placards must remain placarded when emptied unless it:
The following bulk packagings may be placarded on only two opposite sides or may be labeled instead of placarded:
Flexible bulk containers may be placarded in two opposing positions.
Freight containers and aircraft unit load devices (172.512)
A freight container or aircraft unit load device with a capacity less than 640 cubic feet (18 m3) is required to display one placard as specified in Section 172.504. This requirement does not apply if the freight container or unit load device:
Freight containers with a capacity of less than 640 cubic feet that are not transported by air do not have to be placarded — they may be labeled instead.